μ4-Orthothiocarbonato-tetrakis[tricarbonyliron(I)](2 Fe—Fe)

μ4-Orthothiocarbonato-tetrakis[tricarbonyliron(I)](2 Fe—Fe)

The fused bis-butterfly-shaped title compound, [Fe4(CS4)(CO)12], possesses an orthothiocarbonate (CS4 4−) ligand that acts as a bridge between two Fe2(CO)6 units. A short intramolecular S⋯S contact [2.6984 (8) and 2.6977 (8) Å] occurs in each S2Fe2(CO)6 fragment.

Bibliographic Details
Main Authors:	Shi, Yao-Cheng, Cheng, Huan-Ren, Yuan, Li-Min, Li, Qian-Kun
Format:	Online
Language:	English
Published:	International Union of Crystallography 2011
Online Access:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246959/

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