Hepta­carbonyl­bis­(μ-propane-1,3-di­thiol­ato)triiron(I,II)(2 Fe—Fe)

The trinuclear title compound, [Fe3(C3H6S2)2(CO)7], is a mixed-valent FeI/FeII complex and crystallizes with two mol­ecules of similar configuration in the asymmetric unit. The three Fe atoms in each mol­ecule display a bent arrangement [Fe—Fe—Fe = 156.22 (4) and 157.06 (3)°]. Both outer FeI atoms a...

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Bibliographic Details
Main Authors: Hu, Mingqiang, Ma, Chengbing, Wen, Huimin, Cui, Honghua, Chen, Changneng
Format: Online
Language:English
Published: International Union of Crystallography 2014
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998616/