Undecacarbonyl-μ2-methanethiolato-μ2-[(pyridin-2-yl)methanethiolato]-μ4-sulfido-tetrairon(II)(2 Fe—Fe)
The title compound, [Fe4(C6H6NS)(CH3S)S(CO)11], comprises two butterfly-shaped sub-cluster cores, Fe2S2N and Fe2S2, joined together by a spiro-type μ4-S atom. The (pyridin-2-yl)methanethiolate ligand is attached to the Fe2(CO)5 unit in a μ-κN:κ2 S mode, and the methanethiolate li...
| Main Authors: | , , , |
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| Format: | Online |
| Language: | English |
| Published: |
International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238668/ |