μ4-Orthothiocarbonato-tetrakis[tricarbonyliron(I)](2 Fe—Fe)
The fused bis-butterfly-shaped title compound, [Fe4(CS4)(CO)12], possesses an orthothiocarbonate (CS4 4−) ligand that acts as a bridge between two Fe2(CO)6 units. A short intramolecular S⋯S contact [2.6984 (8) and 2.6977 (8) Å] occurs in each S2Fe2(CO)6 fragment.
| Main Authors: | , , , |
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| Format: | Online |
| Language: | English |
| Published: |
International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246959/ |