Switchable synthesis of Z-homoallylic boronates and E-allylic boronates by enantioselective copper-catalyzed 1,6-boration

The enantioselective Cu-catalyzed 1,6-boration of (E,E) α,β,γ,δ-unsaturated ketones is described, which gives homoallylic boronates with high enantiomeric purity and unexpectedly high Zselectivity. By changing the solvent, the outcome can be altered to give E-allylic boronates.

Bibliographic Details
Main Authors:	Luo, Yunfei, Wales, Steven M., Korkis, Stamatis E., Roy, Iain D., Lewis, William, Lam, Hon Wai
Format:	Article
Language:	English
Published:	Wiley 2018
Online Access:	http://eprints.nottingham.ac.uk/51268/ http://eprints.nottingham.ac.uk/51268/ http://eprints.nottingham.ac.uk/51268/ http://eprints.nottingham.ac.uk/51268/1/Hon%20Lam%20Switchable%20Synhesis%20of%20Z-Homoallylic.pdf

id	nottingham-51268
recordtype	eprints
spelling	nottingham-512682018-07-02T09:19:31Z http://eprints.nottingham.ac.uk/51268/ Switchable synthesis of Z-homoallylic boronates and E-allylic boronates by enantioselective copper-catalyzed 1,6-boration Luo, Yunfei Wales, Steven M. Korkis, Stamatis E. Roy, Iain D. Lewis, William Lam, Hon Wai The enantioselective Cu-catalyzed 1,6-boration of (E,E) α,β,γ,δ-unsaturated ketones is described, which gives homoallylic boronates with high enantiomeric purity and unexpectedly high Zselectivity. By changing the solvent, the outcome can be altered to give E-allylic boronates. Wiley 2018-06-12 Article PeerReviewed application/pdf en http://eprints.nottingham.ac.uk/51268/1/Hon%20Lam%20Switchable%20Synhesis%20of%20Z-Homoallylic.pdf Luo, Yunfei and Wales, Steven M. and Korkis, Stamatis E. and Roy, Iain D. and Lewis, William and Lam, Hon Wai (2018) Switchable synthesis of Z-homoallylic boronates and E-allylic boronates by enantioselective copper-catalyzed 1,6-boration. Chemistry - a European Journal, 24 (33). pp. 8315-8319. ISSN 1521-3765 https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201801804 doi:10.1002/chem.201801804 doi:10.1002/chem.201801804
repository_type	Digital Repository
institution_category	Local University
institution	University of Nottingham Malaysia Campus
building	Nottingham Research Data Repository
collection	Online Access
language	English
description	The enantioselective Cu-catalyzed 1,6-boration of (E,E) α,β,γ,δ-unsaturated ketones is described, which gives homoallylic boronates with high enantiomeric purity and unexpectedly high Zselectivity. By changing the solvent, the outcome can be altered to give E-allylic boronates.
format	Article
author	Luo, Yunfei Wales, Steven M. Korkis, Stamatis E. Roy, Iain D. Lewis, William Lam, Hon Wai
spellingShingle	Luo, Yunfei Wales, Steven M. Korkis, Stamatis E. Roy, Iain D. Lewis, William Lam, Hon Wai Switchable synthesis of Z-homoallylic boronates and E-allylic boronates by enantioselective copper-catalyzed 1,6-boration
author_facet	Luo, Yunfei Wales, Steven M. Korkis, Stamatis E. Roy, Iain D. Lewis, William Lam, Hon Wai
author_sort	Luo, Yunfei
title	Switchable synthesis of Z-homoallylic boronates and E-allylic boronates by enantioselective copper-catalyzed 1,6-boration
title_short	Switchable synthesis of Z-homoallylic boronates and E-allylic boronates by enantioselective copper-catalyzed 1,6-boration
title_full	Switchable synthesis of Z-homoallylic boronates and E-allylic boronates by enantioselective copper-catalyzed 1,6-boration
title_fullStr	Switchable synthesis of Z-homoallylic boronates and E-allylic boronates by enantioselective copper-catalyzed 1,6-boration
title_full_unstemmed	Switchable synthesis of Z-homoallylic boronates and E-allylic boronates by enantioselective copper-catalyzed 1,6-boration
title_sort	switchable synthesis of z-homoallylic boronates and e-allylic boronates by enantioselective copper-catalyzed 1,6-boration
publisher	Wiley
publishDate	2018
url	http://eprints.nottingham.ac.uk/51268/ http://eprints.nottingham.ac.uk/51268/ http://eprints.nottingham.ac.uk/51268/ http://eprints.nottingham.ac.uk/51268/1/Hon%20Lam%20Switchable%20Synhesis%20of%20Z-Homoallylic.pdf
first_indexed	2018-09-06T14:19:33Z
last_indexed	2018-09-06T14:19:33Z
_version_	1610868141796098048

Switchable synthesis of Z-homoallylic boronates and E-allylic boronates by enantioselective copper-catalyzed 1,6-boration

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