Enantioselective synthesis of allylboronates and allylic alcohols by copper-catalyzed 1,6-boration
Chiral secondary allylboronates are obtained in high enantioselectivities by the copper-catalyzed 1,6-boration of electron-deficient dienes with B2(pin)2. The reactions proceed efficiently using catalyst loadings as low as 0.0049 mol%. The allylboronates may be oxidized to the allylic alcohols, and...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley-VCH Verlag
2014
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| Online Access: | http://eprints.nottingham.ac.uk/31656/ http://eprints.nottingham.ac.uk/31656/ http://eprints.nottingham.ac.uk/31656/ http://eprints.nottingham.ac.uk/31656/1/HWL%20Yunfei%20Iain%20Amael%201%2C6-Boration%20ACIE%20Submission%20%28accepted%29.pdf |