One-carbon oxidative annulations of 1,3-enynes by catalytic C–H functionalization and 1,4-rhodium(III) migration
Rhodium(III)-catalyzed C-H functionalization-oxidative annulations of aromatic substrates with 1,3-enynes that contain allylic hydrogen atoms cis to the alkyne are described. The key step in these reactions is an alkenyl-to-allyl 1,4-rhodium(III) migration to give electrophilic pi-allylrhodium(III)...
Main Authors: | , |
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Format: | Article |
Language: | English |
Published: |
Wiley
2018
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Online Access: | http://eprints.nottingham.ac.uk/49295/ http://eprints.nottingham.ac.uk/49295/ http://eprints.nottingham.ac.uk/49295/ http://eprints.nottingham.ac.uk/49295/1/Hon%20Lam%20One-Carbon%20Oxidative%20Annulations.pdf |