Synthesis of spirocyclic enones by rhodium-catalyzed dearomatizing oxidative annulation of 2-alkenylphenols with alkynes and enynes
The dearomatizing oxidative annulation of 2-alkenylphenols with alkynes and enynes proceeds with high yields and regioselectivities under Rh(III) catalysis. These reactions are successful using Cu(OAc)2 or air as the stoichiometric oxidant, and provide spirocyclic enones, the basic ring system of wh...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley-VCH Verlag
2014
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| Online Access: | http://eprints.nottingham.ac.uk/31657/ http://eprints.nottingham.ac.uk/31657/ http://eprints.nottingham.ac.uk/31657/ http://eprints.nottingham.ac.uk/31657/1/HWL%20SzymonDanDave%20Rh-Catalyzed%20Dearomatizing%20Spiroannulation%20CEJ%20submission.pdf |