Enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and Imines by alkenyl-to-allyl 1,4-rhodium(I) migration
A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1,3-enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl-to-allyl 1,4-rhodium(I) migration.
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley-VCH Verlag
2017
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| Online Access: | http://eprints.nottingham.ac.uk/47300/ http://eprints.nottingham.ac.uk/47300/ http://eprints.nottingham.ac.uk/47300/ http://eprints.nottingham.ac.uk/47300/8/Callingham_et_al-2017-Angewandte_Chemie_International_Edition.pdf |