Enantioselective Synthesis of Spiroindenes by Enol-Directed Rhodium(III)-Catalyzed C–H Functionalization and Spiroannulation
Chiral cyclopentadienyl rhodium complexes promote highly enantioselective enol-directed C(sp2)-H functionalization and oxidative annulation with alkynes to give spiroindenes containing all-carbon quaternary stereocenters. High selectivity between two possible directing groups, as well as control of...
| Main Authors: | , , , |
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| Format: | Online |
| Language: | English |
| Published: |
WILEY-VCH Verlag
2015
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4648053/ |