Crystal structure of di­chlorido­(4,11-dimethyl-1,4,8,11-tetra­aza­bicyclo­[6.6.2]hexa­deca­ne)iron(III) hexa­fluorido­phosphate

Crystal structure of di­chlorido­(4,11-dimethyl-1,4,8,11-tetra­aza­bicyclo­[6.6.2]hexa­deca­ne)iron(III) hexa­fluorido­phosphate

In contrast to other similar compounds, [FeCl2(C14H30N4)]PF6 is a monomer. Comparison with the mononuclear Fe2+ complex of the same ligand shows that the smaller Fe3+ ion is more fully engulfed by the cavity of the bicyclic ligand. Comparison with the μ-oxo dinuclear complex of an unsubstituted liga...

Full description

Bibliographic Details
Main Authors: Funwie, Neil L., Cain, Amy N., Fanning, Brian Z., Hageman, Serena A., Mullens, Malorie, Roberts, Travis K., Turner, Daniel J., Valdez, Cammi N., Vaughan, Robert W., Ermias, Henok G., Silversides, Jon D., Archibald, Stephen J., Hubin, Timothy J., Prior, Timothy J.
Format: Online
Language:English
Published: International Union of Crystallography 2015
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555389/

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555389/

Similar Items