Hexa­kis­(dimethyl sulfoxide-κO)calcium μ6-oxido-dodeca­kis-μ2-oxido-hexa­oxido­hexa­tungstate(VI)

In the title compound, [Ca(C2H6OS)6][W6O19], the cation and anion both have a crystallographically imposed centre of symmetry. The CaII atom in the cation is coordinated by six O atoms from six dimethyl sulfoxide ligands in a distorted octa­hedral geometry. The [W6O19]2− isopolyanion possesses the w...

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Bibliographic Details
Main Author: Zhang, Jinfang
Format: Online
Language:English
Published: International Union of Crystallography 2012
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344417/