Crystal structure of pentapotassium dihydrogen nonavanadato(V)platinate(IV) nonahydrate
The polyanion in K5[H2PtV9O28]·9H2O has approximate mm2 (C 2v) symmetry. The two platinum-bound μ2-O atoms are protonated in the polyanion. The heteropolyanions form inversion-generated dimers, {[H2PtV9O28]2}10−, held together by μ2-O—H⋯μ2-O and μ2-O—H⋯μ3-O hydrogen bonds.
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2015
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459313/ |
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pubmed-4459313 |
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oai_dc |
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pubmed-44593132015-06-18 Crystal structure of pentapotassium dihydrogen nonavanadato(V)platinate(IV) nonahydrate Joo, Hea-Chung Lee, Uk Research Communications The polyanion in K5[H2PtV9O28]·9H2O has approximate mm2 (C 2v) symmetry. The two platinum-bound μ2-O atoms are protonated in the polyanion. The heteropolyanions form inversion-generated dimers, {[H2PtV9O28]2}10−, held together by μ2-O—H⋯μ2-O and μ2-O—H⋯μ3-O hydrogen bonds. International Union of Crystallography 2015-05-20 /pmc/articles/PMC4459313/ /pubmed/26090141 http://dx.doi.org/10.1107/S2056989015009135 Text en © Joo and Lee 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Joo, Hea-Chung Lee, Uk |
| spellingShingle |
Joo, Hea-Chung Lee, Uk Crystal structure of pentapotassium dihydrogen nonavanadato(V)platinate(IV) nonahydrate |
| author_facet |
Joo, Hea-Chung Lee, Uk |
| author_sort |
Joo, Hea-Chung |
| title |
Crystal structure of pentapotassium dihydrogen nonavanadato(V)platinate(IV) nonahydrate |
| title_short |
Crystal structure of pentapotassium dihydrogen nonavanadato(V)platinate(IV) nonahydrate |
| title_full |
Crystal structure of pentapotassium dihydrogen nonavanadato(V)platinate(IV) nonahydrate |
| title_fullStr |
Crystal structure of pentapotassium dihydrogen nonavanadato(V)platinate(IV) nonahydrate |
| title_full_unstemmed |
Crystal structure of pentapotassium dihydrogen nonavanadato(V)platinate(IV) nonahydrate |
| title_sort |
crystal structure of pentapotassium dihydrogen nonavanadato(v)platinate(iv) nonahydrate |
| description |
The polyanion in K5[H2PtV9O28]·9H2O has approximate mm2 (C
2v) symmetry. The two platinum-bound μ2-O atoms are protonated in the polyanion. The heteropolyanions form inversion-generated dimers, {[H2PtV9O28]2}10−, held together by μ2-O—H⋯μ2-O and μ2-O—H⋯μ3-O hydrogen bonds. |
| publisher |
International Union of Crystallography |
| publishDate |
2015 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459313/ |
| _version_ |
1613232898052194304 |