Crystal structure of pentapotassium dihydrogen nonavanadato(V)platinate(IV) nonahydrate
The polyanion in K5[H2PtV9O28]·9H2O has approximate mm2 (C 2v) symmetry. The two platinum-bound μ2-O atoms are protonated in the polyanion. The heteropolyanions form inversion-generated dimers, {[H2PtV9O28]2}10−, held together by μ2-O—H⋯μ2-O and μ2-O—H⋯μ3-O hydrogen bonds.
| Main Authors: | , |
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| Format: | Online |
| Language: | English |
| Published: |
International Union of Crystallography
2015
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459313/ |