The structure of metallo-DNA with consecutive thymine–HgII–thymine base pairs explains positive entropy for the metallo base pair formation

The structure of metallo-DNA with consecutive thymine–HgII–thymine base pairs explains positive entropy for the metallo base pair formation

We have determined the three-dimensional (3D) structure of DNA duplex that includes tandem HgII-mediated T–T base pairs (thymine–HgII–thymine, T–HgII–T) with NMR spectroscopy in solution. This is the first 3D structure of metallo-DNA (covalently metallated DNA) composed exclusively of ‘NATURAL’ base...

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Bibliographic Details
Main Authors: Yamaguchi, Hiroshi, Šebera, Jakub, Kondo, Jiro, Oda, Shuji, Komuro, Tomoyuki, Kawamura, Takuya, Dairaku, Takenori, Kondo, Yoshinori, Okamoto, Itaru, Ono, Akira, Burda, Jaroslav V., Kojima, Chojiro, Sychrovský, Vladimír, Tanaka, Yoshiyuki
Format: Online
Language:English
Published: Oxford University Press 2014
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3973346/

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