[meso-5,10,15,20-Tetrakis(3-methylthiophen-2-yl)porphyrinato-κ4
N,N′,N′′,N′′′]nickel(II) benzene hemisolvate

[meso-5,10,15,20-Tetrakis(3-methylthiophen-2-yl)porphyrinato-κ4 N,N′,N′′,N′′′]nickel(II) benzene hemisolvate

In the title compound, [Ni(C40H28N4S4)]·0.5C6H6, the NiII atom is in a square-planar geometry defined by four pyrrole N atoms. There is considerable buckling in the porphyrin ring with the dihedral angles between the N4 donor set and the pyrrole rings being in the range 16.24 (5)–22.47 (5)°. Each of...

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Bibliographic Details
Main Authors:	Prasath, R., Bhavana, P., Gupta, Sushil K., Butcher, Ray J.
Format:	Online
Language:	English
Published:	International Union of Crystallography 2013
Online Access:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884990/

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