[meso-5,10,15,20-Tetra­kis(5-bromo­thio­phen-2-yl)porphyrinato-κ4 N,N′,N′′,N′′′]nickel(II)

[meso-5,10,15,20-Tetra­kis(5-bromo­thio­phen-2-yl)porphyrinato-κ4 N,N′,N′′,N′′′]nickel(II)

The NiII atom in the title porphyrin complex, [Ni(C36H16Br4N4S4)], is in a square-planar geometry defined by four pyrrole N atoms. There is considerable buckling in the porphyrin ring with the dihedral angles between the N4 donor set and the pyrrole rings being in the range 17.0 (3)–18.8 (3)°. Each...

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Bibliographic Details
Main Authors: Prasath, R., Bhavana, P., Ng, Seik Weng, Tiekink, Edward R. T.
Format: Online
Language:English
Published: International Union of Crystallography 2012
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343861/

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343861/

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