Octa­kis(dimethyl sulfoxide-κO)cerium(III) μ6-oxido-dodeca-μ2-oxido-hexa­oxidohexa­molybdate(VI) dimethyl sulfoxide tetrasolvate

The title complex, [Ce(C2H6OS)8]2[Mo6O19]3·4C2H6OS, was obtained as a byproduct of the reaction of [(C4H9)4N]2[Mo6O19] with Ce(NO3)3·6H2O and phthalic acid in dimethyl­sulfoxide solution. The asymmetric unit consists of a complex [Ce(C2H6OS)8]3+ cation, one and a half of the Lindqvist-type [Mo6O19]2...

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Bibliographic Details
Main Authors: Ben Khélifa, Arbia, Giorgi, Michel, Belkhiria, Mohamed Salah
Format: Online
Language:English
Published: International Union of Crystallography 2012
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393199/