Chloridonitrosyl[meso-5,10,15,20-tetrakis(p-tolyl)porphyrinato-κ4 N,N′,N′′,N′′′]osmium(II) tetrahydrofuran tetrasolvate
The title compound, [OsCl(NO)(C48H36N4)]·4C4H8O, is a six-coordinate osmium(II) porphyrin complex with nitrosyl (NO) and chloride (Cl) ligands trans to each other in an octahedral geometry. The metal complex lies on a fourfold rotation axis that passes through the Os, N, O and Cl atoms. The NO and...
| Main Authors: | , , , |
|---|---|
| Format: | Online |
| Language: | English |
| Published: |
International Union of Crystallography
2011
|
| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051540/ |
| id |
pubmed-3051540 |
|---|---|
| recordtype |
oai_dc |
| spelling |
pubmed-30515402011-04-26 Chloridonitrosyl[meso-5,10,15,20-tetrakis(p-tolyl)porphyrinato-κ4 N,N′,N′′,N′′′]osmium(II) tetrahydrofuran tetrasolvate Chen, Li Xu, Nan Powell, Douglas R. Richter-Addo, George B. Metal-Organic Papers The title compound, [OsCl(NO)(C48H36N4)]·4C4H8O, is a six-coordinate osmium(II) porphyrin complex with nitrosyl (NO) and chloride (Cl) ligands trans to each other in an octahedral geometry. The metal complex lies on a fourfold rotation axis that passes through the Os, N, O and Cl atoms. The NO and Cl ligands are disordered in an 0.511 (12):0.486 (12) ratio. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051540/ /pubmed/21522883 http://dx.doi.org/10.1107/S1600536811001401 Text en © Chen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Chen, Li Xu, Nan Powell, Douglas R. Richter-Addo, George B. |
| spellingShingle |
Chen, Li Xu, Nan Powell, Douglas R. Richter-Addo, George B. Chloridonitrosyl[meso-5,10,15,20-tetrakis(p-tolyl)porphyrinato-κ4 N,N′,N′′,N′′′]osmium(II) tetrahydrofuran tetrasolvate |
| author_facet |
Chen, Li Xu, Nan Powell, Douglas R. Richter-Addo, George B. |
| author_sort |
Chen, Li |
| title |
Chloridonitrosyl[meso-5,10,15,20-tetrakis(p-tolyl)porphyrinato-κ4
N,N′,N′′,N′′′]osmium(II) tetrahydrofuran tetrasolvate |
| title_short |
Chloridonitrosyl[meso-5,10,15,20-tetrakis(p-tolyl)porphyrinato-κ4
N,N′,N′′,N′′′]osmium(II) tetrahydrofuran tetrasolvate |
| title_full |
Chloridonitrosyl[meso-5,10,15,20-tetrakis(p-tolyl)porphyrinato-κ4
N,N′,N′′,N′′′]osmium(II) tetrahydrofuran tetrasolvate |
| title_fullStr |
Chloridonitrosyl[meso-5,10,15,20-tetrakis(p-tolyl)porphyrinato-κ4
N,N′,N′′,N′′′]osmium(II) tetrahydrofuran tetrasolvate |
| title_full_unstemmed |
Chloridonitrosyl[meso-5,10,15,20-tetrakis(p-tolyl)porphyrinato-κ4
N,N′,N′′,N′′′]osmium(II) tetrahydrofuran tetrasolvate |
| title_sort |
chloridonitrosyl[meso-5,10,15,20-tetrakis(p-tolyl)porphyrinato-κ4
n,n′,n′′,n′′′]osmium(ii) tetrahydrofuran tetrasolvate |
| description |
The title compound, [OsCl(NO)(C48H36N4)]·4C4H8O, is a six-coordinate osmium(II) porphyrin complex with nitrosyl (NO) and chloride (Cl) ligands trans to each other in an octahedral geometry. The metal complex lies on a fourfold rotation axis that passes through the Os, N, O and Cl atoms. The NO and Cl ligands are disordered in an 0.511 (12):0.486 (12) ratio. |
| publisher |
International Union of Crystallography |
| publishDate |
2011 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051540/ |
| _version_ |
1611443642687291392 |