Synthesis and characterization of dimethyltin(IV) complex with 2-methylpyridylbenzhydrazone (AcPyBzh): Crystal structure of [Me2SnCl (AcPyBzh)]
The reaction of dimethyltin(IV) dihalide with 2-methylpyridylbenzhydrazone (AcPyBzh) afforded the complex compound [Me2SnCl(AcPyBzh)]. The complex was characterized by IR, 1H and 13C-{ 1H} NMR spectroscopic techniques and elemental analyses. The crystal structure of [Me2SnCL(AcPyBzh)] has been deter...
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| Format: | Article |
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2005
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| Online Access: | http://eprints.utm.my/7797/ |
| _version_ | 1848891546873626624 |
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| author | Affan, M.A Ahmad, Fasihuddin Bin Hitam, R.B Shamsuddin, M.B Yamin, Bohari Mohamad |
| author_facet | Affan, M.A Ahmad, Fasihuddin Bin Hitam, R.B Shamsuddin, M.B Yamin, Bohari Mohamad |
| author_sort | Affan, M.A |
| building | UTeM Institutional Repository |
| collection | Online Access |
| description | The reaction of dimethyltin(IV) dihalide with 2-methylpyridylbenzhydrazone (AcPyBzh) afforded the complex compound [Me2SnCl(AcPyBzh)]. The complex was characterized by IR, 1H and 13C-{ 1H} NMR spectroscopic techniques and elemental analyses. The crystal structure of [Me2SnCL(AcPyBzh)] has been determined. The AcPyBzh anion in this complex acts as a monobasic NNO bidentate ligand, the tin(IV) lying in an elongated distrorted trigonal bipyramidal environment where the azomethine nitrogen and amidate oxygen, together with the two-methyl carbons, are in the equatorial plane, whereas the chloride is the apical ligand. The crystal is monoclinic, space group P2(I)/n, with a = 12.0945 (3), b = 7.5167 (2), c = 19.9795 (4) Å, α = 90°, β= 105.85°, γ = 90°.
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| first_indexed | 2025-11-15T20:59:42Z |
| format | Article |
| id | utm-7797 |
| institution | Universiti Teknologi Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-15T20:59:42Z |
| publishDate | 2005 |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | utm-77972017-04-25T06:44:55Z http://eprints.utm.my/7797/ Synthesis and characterization of dimethyltin(IV) complex with 2-methylpyridylbenzhydrazone (AcPyBzh): Crystal structure of [Me2SnCl (AcPyBzh)] Affan, M.A Ahmad, Fasihuddin Bin Hitam, R.B Shamsuddin, M.B Yamin, Bohari Mohamad QD Chemistry The reaction of dimethyltin(IV) dihalide with 2-methylpyridylbenzhydrazone (AcPyBzh) afforded the complex compound [Me2SnCl(AcPyBzh)]. The complex was characterized by IR, 1H and 13C-{ 1H} NMR spectroscopic techniques and elemental analyses. The crystal structure of [Me2SnCL(AcPyBzh)] has been determined. The AcPyBzh anion in this complex acts as a monobasic NNO bidentate ligand, the tin(IV) lying in an elongated distrorted trigonal bipyramidal environment where the azomethine nitrogen and amidate oxygen, together with the two-methyl carbons, are in the equatorial plane, whereas the chloride is the apical ligand. The crystal is monoclinic, space group P2(I)/n, with a = 12.0945 (3), b = 7.5167 (2), c = 19.9795 (4) Å, α = 90°, β= 105.85°, γ = 90°. 2005-11 Article PeerReviewed Affan, M.A and Ahmad, Fasihuddin Bin and Hitam, R.B and Shamsuddin, M.B and Yamin, Bohari Mohamad (2005) Synthesis and characterization of dimethyltin(IV) complex with 2-methylpyridylbenzhydrazone (AcPyBzh): Crystal structure of [Me2SnCl (AcPyBzh)]. Pakistan Journal of Scientific and Industrial Research, 48 . 381-385 . https://pure.utm.my/en/publications/synthesis-and-characterization-of-dimethyltiniv-complex-with-2-me |
| spellingShingle | QD Chemistry Affan, M.A Ahmad, Fasihuddin Bin Hitam, R.B Shamsuddin, M.B Yamin, Bohari Mohamad Synthesis and characterization of dimethyltin(IV) complex with 2-methylpyridylbenzhydrazone (AcPyBzh): Crystal structure of [Me2SnCl (AcPyBzh)] |
| title | Synthesis and characterization of dimethyltin(IV) complex with 2-methylpyridylbenzhydrazone (AcPyBzh): Crystal structure of [Me2SnCl (AcPyBzh)] |
| title_full | Synthesis and characterization of dimethyltin(IV) complex with 2-methylpyridylbenzhydrazone (AcPyBzh): Crystal structure of [Me2SnCl (AcPyBzh)] |
| title_fullStr | Synthesis and characterization of dimethyltin(IV) complex with 2-methylpyridylbenzhydrazone (AcPyBzh): Crystal structure of [Me2SnCl (AcPyBzh)] |
| title_full_unstemmed | Synthesis and characterization of dimethyltin(IV) complex with 2-methylpyridylbenzhydrazone (AcPyBzh): Crystal structure of [Me2SnCl (AcPyBzh)] |
| title_short | Synthesis and characterization of dimethyltin(IV) complex with 2-methylpyridylbenzhydrazone (AcPyBzh): Crystal structure of [Me2SnCl (AcPyBzh)] |
| title_sort | synthesis and characterization of dimethyltin(iv) complex with 2-methylpyridylbenzhydrazone (acpybzh): crystal structure of [me2sncl (acpybzh)] |
| topic | QD Chemistry |
| url | http://eprints.utm.my/7797/ http://eprints.utm.my/7797/ |