Synthesis Of Microwave-Assisted Coconut Shell Based Activated Carbon For Removal Of Methylene Blue Dye From Aqueous Solution

The hazardous dye effluent from the textile, paper, cosmetic and food processing plant have become a major concern because of the toxicity to the environment. This study aims to synthesis activated carbon (AC) derived from coconut shell (CS) in order to remove methylene blue (MB) dye from aqueous...

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Main Author: Nordin, Nazatul Shima
Format: Monograph
Language:English
Published: Universiti Sains Malaysia 2018
Subjects:
Online Access:http://eprints.usm.my/54089/
http://eprints.usm.my/54089/1/Synthesis%20Of%20Microwave-Assisted%20Coconut%20Shell%20Based%20Activated%20Carbon%20For%20Removal%20Of%20Methylene%20Blue%20Dye%20From%20Aqueous%20Solution_Nazatul%20Shima%20Nordin_K4_2018.pdf
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author Nordin, Nazatul Shima
author_facet Nordin, Nazatul Shima
author_sort Nordin, Nazatul Shima
building USM Institutional Repository
collection Online Access
description The hazardous dye effluent from the textile, paper, cosmetic and food processing plant have become a major concern because of the toxicity to the environment. This study aims to synthesis activated carbon (AC) derived from coconut shell (CS) in order to remove methylene blue (MB) dye from aqueous solution. The coconut shell based activated carbon (CSAC) was prepared via physical activation process by using microwave irradiation under the flow of carbon dioxide (CO2) gasification. The effect of contact time (0-24 hours), initial concentration (25mg/L-300mg/L) and temperature (30˚C, 45˚C and 60˚C) on the adsorption performance of CSAC were evaluated. Optimum condition for the CSAC preparation was obtained at power and time of 440W and 6 minutes, respectively by using response surface methodology (RSM). The optimized CSAC has high BET surface area, mesopore surface area, total pore volume and fixed carbon of 658.44m2/g, 502.31m2/g, 0.4898cm3/g and 82.13%, respectively. The pore for CSAC was the mesoporous type with pore diameter of 5.72nm. Langmuir isotherm and pseudo-second-order was found as the best fitted model for MB adsorption equilibrium and kinetic onto CSAC. The monolayer adsorption capacity of MB onto CSAC was 217.3 mg/g. The adsorption system was endothermic in nature and it was governed by physisorption. The mechanism studies revealed that the adsorption process of MB onto CSAC were controlled by film diffusion mechanism.
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format Monograph
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institution Universiti Sains Malaysia
institution_category Local University
language English
last_indexed 2025-11-15T18:39:11Z
publishDate 2018
publisher Universiti Sains Malaysia
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spelling usm-540892022-08-15T08:26:25Z http://eprints.usm.my/54089/ Synthesis Of Microwave-Assisted Coconut Shell Based Activated Carbon For Removal Of Methylene Blue Dye From Aqueous Solution Nordin, Nazatul Shima T Technology TP Chemical Technology The hazardous dye effluent from the textile, paper, cosmetic and food processing plant have become a major concern because of the toxicity to the environment. This study aims to synthesis activated carbon (AC) derived from coconut shell (CS) in order to remove methylene blue (MB) dye from aqueous solution. The coconut shell based activated carbon (CSAC) was prepared via physical activation process by using microwave irradiation under the flow of carbon dioxide (CO2) gasification. The effect of contact time (0-24 hours), initial concentration (25mg/L-300mg/L) and temperature (30˚C, 45˚C and 60˚C) on the adsorption performance of CSAC were evaluated. Optimum condition for the CSAC preparation was obtained at power and time of 440W and 6 minutes, respectively by using response surface methodology (RSM). The optimized CSAC has high BET surface area, mesopore surface area, total pore volume and fixed carbon of 658.44m2/g, 502.31m2/g, 0.4898cm3/g and 82.13%, respectively. The pore for CSAC was the mesoporous type with pore diameter of 5.72nm. Langmuir isotherm and pseudo-second-order was found as the best fitted model for MB adsorption equilibrium and kinetic onto CSAC. The monolayer adsorption capacity of MB onto CSAC was 217.3 mg/g. The adsorption system was endothermic in nature and it was governed by physisorption. The mechanism studies revealed that the adsorption process of MB onto CSAC were controlled by film diffusion mechanism. Universiti Sains Malaysia 2018-06-01 Monograph NonPeerReviewed application/pdf en http://eprints.usm.my/54089/1/Synthesis%20Of%20Microwave-Assisted%20Coconut%20Shell%20Based%20Activated%20Carbon%20For%20Removal%20Of%20Methylene%20Blue%20Dye%20From%20Aqueous%20Solution_Nazatul%20Shima%20Nordin_K4_2018.pdf Nordin, Nazatul Shima (2018) Synthesis Of Microwave-Assisted Coconut Shell Based Activated Carbon For Removal Of Methylene Blue Dye From Aqueous Solution. Project Report. Universiti Sains Malaysia, Pusat Pengajian Kejuruteraan Kimia. (Submitted)
spellingShingle T Technology
TP Chemical Technology
Nordin, Nazatul Shima
Synthesis Of Microwave-Assisted Coconut Shell Based Activated Carbon For Removal Of Methylene Blue Dye From Aqueous Solution
title Synthesis Of Microwave-Assisted Coconut Shell Based Activated Carbon For Removal Of Methylene Blue Dye From Aqueous Solution
title_full Synthesis Of Microwave-Assisted Coconut Shell Based Activated Carbon For Removal Of Methylene Blue Dye From Aqueous Solution
title_fullStr Synthesis Of Microwave-Assisted Coconut Shell Based Activated Carbon For Removal Of Methylene Blue Dye From Aqueous Solution
title_full_unstemmed Synthesis Of Microwave-Assisted Coconut Shell Based Activated Carbon For Removal Of Methylene Blue Dye From Aqueous Solution
title_short Synthesis Of Microwave-Assisted Coconut Shell Based Activated Carbon For Removal Of Methylene Blue Dye From Aqueous Solution
title_sort synthesis of microwave-assisted coconut shell based activated carbon for removal of methylene blue dye from aqueous solution
topic T Technology
TP Chemical Technology
url http://eprints.usm.my/54089/
http://eprints.usm.my/54089/1/Synthesis%20Of%20Microwave-Assisted%20Coconut%20Shell%20Based%20Activated%20Carbon%20For%20Removal%20Of%20Methylene%20Blue%20Dye%20From%20Aqueous%20Solution_Nazatul%20Shima%20Nordin_K4_2018.pdf