Biochars as Potential Adsorbers of CH4, CO2 and H2S

Methane gas, as one of the major biogases, is a potential source of renewable energy for power production. Biochar can be readily used to purify biogas contaminants such as H2S and CO2. This study assessed the adsorption of CH4, H2S, and CO2 onto four different types of biochars. The adsorption d...

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Main Authors: Sethupathi, Sumathi, Ming, Zhang, Rajapaksha, Anushka Upamali, Sang, Ryong Lee, Mohamad Nor, Norhusna, Mohamed, Abdul Rahman, Al-Wabel, Mohammad, Sang, Soo Lee, Yong, Sik Ok
Format: Article
Language:English
Published: MDPI 2017
Subjects:
Online Access:http://eprints.usm.my/38399/
http://eprints.usm.my/38399/1/Biochars_as_Potential_Adsorbers_of_CH4%2C_CO2_and_H2S.pdf
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author Sethupathi, Sumathi
Ming, Zhang
Rajapaksha, Anushka Upamali
Sang, Ryong Lee
Mohamad Nor, Norhusna
Mohamed, Abdul Rahman
Al-Wabel, Mohammad
Sang, Soo Lee
Yong, Sik Ok
author_facet Sethupathi, Sumathi
Ming, Zhang
Rajapaksha, Anushka Upamali
Sang, Ryong Lee
Mohamad Nor, Norhusna
Mohamed, Abdul Rahman
Al-Wabel, Mohammad
Sang, Soo Lee
Yong, Sik Ok
author_sort Sethupathi, Sumathi
building USM Institutional Repository
collection Online Access
description Methane gas, as one of the major biogases, is a potential source of renewable energy for power production. Biochar can be readily used to purify biogas contaminants such as H2S and CO2. This study assessed the adsorption of CH4, H2S, and CO2 onto four different types of biochars. The adsorption dynamics of biochars were investigated in a fixed-bed column, by determining the breakthrough curves and adsorption capacities of biochars. The physicochemical properties of biochars were considered to justify the adsorption performance. The results showed that CH4 was not adsorbed well by the subjected biochars whereas CO2 and H2S were successfully captured. The H2S and CO2 breakthrough capacity were related to both the surface adsorption and chemical reaction. The adsorption capacity was in the following order: perilla > soybean stover > Korean oak > Japanese oak biochars. The simultaneous adsorption also leads to a competition of sorption sites. Biochars are a promising material for the biogas purification industry.
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publishDate 2017
publisher MDPI
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spelling usm-383992019-04-17T02:43:44Z http://eprints.usm.my/38399/ Biochars as Potential Adsorbers of CH4, CO2 and H2S Sethupathi, Sumathi Ming, Zhang Rajapaksha, Anushka Upamali Sang, Ryong Lee Mohamad Nor, Norhusna Mohamed, Abdul Rahman Al-Wabel, Mohammad Sang, Soo Lee Yong, Sik Ok TP1-1185 Chemical technology Methane gas, as one of the major biogases, is a potential source of renewable energy for power production. Biochar can be readily used to purify biogas contaminants such as H2S and CO2. This study assessed the adsorption of CH4, H2S, and CO2 onto four different types of biochars. The adsorption dynamics of biochars were investigated in a fixed-bed column, by determining the breakthrough curves and adsorption capacities of biochars. The physicochemical properties of biochars were considered to justify the adsorption performance. The results showed that CH4 was not adsorbed well by the subjected biochars whereas CO2 and H2S were successfully captured. The H2S and CO2 breakthrough capacity were related to both the surface adsorption and chemical reaction. The adsorption capacity was in the following order: perilla > soybean stover > Korean oak > Japanese oak biochars. The simultaneous adsorption also leads to a competition of sorption sites. Biochars are a promising material for the biogas purification industry. MDPI 2017 Article PeerReviewed application/pdf en http://eprints.usm.my/38399/1/Biochars_as_Potential_Adsorbers_of_CH4%2C_CO2_and_H2S.pdf Sethupathi, Sumathi and Ming, Zhang and Rajapaksha, Anushka Upamali and Sang, Ryong Lee and Mohamad Nor, Norhusna and Mohamed, Abdul Rahman and Al-Wabel, Mohammad and Sang, Soo Lee and Yong, Sik Ok (2017) Biochars as Potential Adsorbers of CH4, CO2 and H2S. Sustainability, 9 (1). pp. 1-10. ISSN 2071-1050 https://doi.org/10.3390/su9010121
spellingShingle TP1-1185 Chemical technology
Sethupathi, Sumathi
Ming, Zhang
Rajapaksha, Anushka Upamali
Sang, Ryong Lee
Mohamad Nor, Norhusna
Mohamed, Abdul Rahman
Al-Wabel, Mohammad
Sang, Soo Lee
Yong, Sik Ok
Biochars as Potential Adsorbers of CH4, CO2 and H2S
title Biochars as Potential Adsorbers of CH4, CO2 and H2S
title_full Biochars as Potential Adsorbers of CH4, CO2 and H2S
title_fullStr Biochars as Potential Adsorbers of CH4, CO2 and H2S
title_full_unstemmed Biochars as Potential Adsorbers of CH4, CO2 and H2S
title_short Biochars as Potential Adsorbers of CH4, CO2 and H2S
title_sort biochars as potential adsorbers of ch4, co2 and h2s
topic TP1-1185 Chemical technology
url http://eprints.usm.my/38399/
http://eprints.usm.my/38399/
http://eprints.usm.my/38399/1/Biochars_as_Potential_Adsorbers_of_CH4%2C_CO2_and_H2S.pdf