Effect of zeolite on the thermal properties of conducting polymer Polypyrrole

This Polypyrrole and Polypyrrole/Zeolite conjugated system were successfully synthesized through the chemical oxidation polymerization method. The structural, morphological and thermal properties of the synthesized compound were characterized by Xray diffraction (XRD) analysis, Field Emission Scanni...

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Main Authors: Mohd Tarmizi, Emma Ziezie, Mohamed Kamari, Halimah, Talib, Zainal Abidin, Mohd Noor, Ikhwan Syafiq
Format: Article
Language:English
Published: 2019
Online Access:http://psasir.upm.edu.my/id/eprint/79561/
http://psasir.upm.edu.my/id/eprint/79561/1/Effect%20of%20zeolite%20on%20the%20thermal%20properties%20of%20conducting%20polymer%20Polypyrrole%20.pdf
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author Mohd Tarmizi, Emma Ziezie
Mohamed Kamari, Halimah
Talib, Zainal Abidin
Mohd Noor, Ikhwan Syafiq
author_facet Mohd Tarmizi, Emma Ziezie
Mohamed Kamari, Halimah
Talib, Zainal Abidin
Mohd Noor, Ikhwan Syafiq
author_sort Mohd Tarmizi, Emma Ziezie
building UPM Institutional Repository
collection Online Access
description This Polypyrrole and Polypyrrole/Zeolite conjugated system were successfully synthesized through the chemical oxidation polymerization method. The structural, morphological and thermal properties of the synthesized compound were characterized by Xray diffraction (XRD) analysis, Field Emission Scanning Electron Microscope (FESEM), Thermogravimetry Analysis (TGA) and Laser Flash Measurement. XRD confirmed the amorphous characteristic peak structure of Polypyrrole conjugated system at two theta ~25o . The incorporation of Zeolite resulted in the presence of sharp peak which implies that Polypyrrole/Zeolite conjugated system has some degree of crystallinity and more ordered arrangement than those Polypyrrole conjugated system. The FESEM morphology showed the formation of Polypyrrole and Polypyrrole/Zeolite conjugated system revealing a globular and coiled structure images. Thermal transport property of thermal diffusivity has been measured ranging from room temperature up to 420 K while thermal stability through thermo gravit metric analysis is measured from room temperature to 1273 K. The incorporation of Zeolite in conducting Polypyrrole shows an enhancement of thermal stability through laser flash measurement measurement and thermogravimetric analysis. As Zeolite content increases in the Polypyrrole/Zeolite samples, the conjugation length increased hence improved the thermal diffusivity and the thermal stability of the sample.
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institution Universiti Putra Malaysia
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spelling upm-795612021-06-28T16:32:08Z http://psasir.upm.edu.my/id/eprint/79561/ Effect of zeolite on the thermal properties of conducting polymer Polypyrrole Mohd Tarmizi, Emma Ziezie Mohamed Kamari, Halimah Talib, Zainal Abidin Mohd Noor, Ikhwan Syafiq This Polypyrrole and Polypyrrole/Zeolite conjugated system were successfully synthesized through the chemical oxidation polymerization method. The structural, morphological and thermal properties of the synthesized compound were characterized by Xray diffraction (XRD) analysis, Field Emission Scanning Electron Microscope (FESEM), Thermogravimetry Analysis (TGA) and Laser Flash Measurement. XRD confirmed the amorphous characteristic peak structure of Polypyrrole conjugated system at two theta ~25o . The incorporation of Zeolite resulted in the presence of sharp peak which implies that Polypyrrole/Zeolite conjugated system has some degree of crystallinity and more ordered arrangement than those Polypyrrole conjugated system. The FESEM morphology showed the formation of Polypyrrole and Polypyrrole/Zeolite conjugated system revealing a globular and coiled structure images. Thermal transport property of thermal diffusivity has been measured ranging from room temperature up to 420 K while thermal stability through thermo gravit metric analysis is measured from room temperature to 1273 K. The incorporation of Zeolite in conducting Polypyrrole shows an enhancement of thermal stability through laser flash measurement measurement and thermogravimetric analysis. As Zeolite content increases in the Polypyrrole/Zeolite samples, the conjugation length increased hence improved the thermal diffusivity and the thermal stability of the sample. 2019-12 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/79561/1/Effect%20of%20zeolite%20on%20the%20thermal%20properties%20of%20conducting%20polymer%20Polypyrrole%20.pdf Mohd Tarmizi, Emma Ziezie and Mohamed Kamari, Halimah and Talib, Zainal Abidin and Mohd Noor, Ikhwan Syafiq (2019) Effect of zeolite on the thermal properties of conducting polymer Polypyrrole. Journal of Multidisciplinary Engineering Science and Technology, 6 (12 spec.). pp. 34-40. ISSN 2458-9403 https://www.jmest.org/vol-6-issue-12-december-2019special-issue/
spellingShingle Mohd Tarmizi, Emma Ziezie
Mohamed Kamari, Halimah
Talib, Zainal Abidin
Mohd Noor, Ikhwan Syafiq
Effect of zeolite on the thermal properties of conducting polymer Polypyrrole
title Effect of zeolite on the thermal properties of conducting polymer Polypyrrole
title_full Effect of zeolite on the thermal properties of conducting polymer Polypyrrole
title_fullStr Effect of zeolite on the thermal properties of conducting polymer Polypyrrole
title_full_unstemmed Effect of zeolite on the thermal properties of conducting polymer Polypyrrole
title_short Effect of zeolite on the thermal properties of conducting polymer Polypyrrole
title_sort effect of zeolite on the thermal properties of conducting polymer polypyrrole
url http://psasir.upm.edu.my/id/eprint/79561/
http://psasir.upm.edu.my/id/eprint/79561/
http://psasir.upm.edu.my/id/eprint/79561/1/Effect%20of%20zeolite%20on%20the%20thermal%20properties%20of%20conducting%20polymer%20Polypyrrole%20.pdf