Impact of ablation time on Cu oxide nanoparticle green synthesis via pulsed laser ablation in liquid media

Large-scale commercial production of nanoparticles via efficient, economical, and environmentally friendly methods is a challenging endeavour. The laser ablation method being a green and potential route of nanoparticles synthesis can be exploited to achieve this end. In this work, we report the abla...

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Main Authors: Al-Jumaili, Batool Eneaze Bandar, Talib, Zainal Abidin, Zakaria, Azmi, Ramizy, Asmiet, Ahmed, Naser Mahmoud, Paiman, Suriati, Liew, Josephine Ying Chyi, Muhd, Ibrahim B., Baqiah, Hussein
Format: Article
Language:English
Published: Springer 2018
Online Access:http://psasir.upm.edu.my/id/eprint/69315/
http://psasir.upm.edu.my/id/eprint/69315/1/Impact%20of%20ablation%20time%20on%20Cu%20oxide%20nanoparticle%20green%20synthesis%20via%20pulsed%20laser%20ablation%20in%20liquid%20media.pdf
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author Al-Jumaili, Batool Eneaze Bandar
Talib, Zainal Abidin
Zakaria, Azmi
Ramizy, Asmiet
Ahmed, Naser Mahmoud
Paiman, Suriati
Liew, Josephine Ying Chyi
Muhd, Ibrahim B.
Baqiah, Hussein
author_facet Al-Jumaili, Batool Eneaze Bandar
Talib, Zainal Abidin
Zakaria, Azmi
Ramizy, Asmiet
Ahmed, Naser Mahmoud
Paiman, Suriati
Liew, Josephine Ying Chyi
Muhd, Ibrahim B.
Baqiah, Hussein
author_sort Al-Jumaili, Batool Eneaze Bandar
building UPM Institutional Repository
collection Online Access
description Large-scale commercial production of nanoparticles via efficient, economical, and environmentally friendly methods is a challenging endeavour. The laser ablation method being a green and potential route of nanoparticles synthesis can be exploited to achieve this end. In this work, we report the ablation of a copper target submerged in distilled water by pulsed Nd:YAG laser. The influence of ablation time on the structure and optical properties of grown copper oxide nanoparticles are studied. Such nanoparticle composition and structure is determined by X-ray diffraction (XRD), Fourier transform infrared, and Raman analyses. Results from transmission electron microscopy images established that synthesised nanoparticles are a spherical shape with average sizes of 24–37 nm. Fluorescence spectra revealed the enhancement of nanoparticle concentration and reduction in the sizes with increasing ablation time, where the optimum ablation time is demonstrated to be 60 min. Photoluminescence spectra exhibited a prominent visible peak (green), which blueshifted from 542 to 537 nm, confirming the shrinkage of copper oxide particle size at higher ablation time. The XRD pattern showed that the prepared nanoparticles possess a single phase of monocline cupric oxide nanostructure.
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spelling upm-693152019-06-12T07:45:25Z http://psasir.upm.edu.my/id/eprint/69315/ Impact of ablation time on Cu oxide nanoparticle green synthesis via pulsed laser ablation in liquid media Al-Jumaili, Batool Eneaze Bandar Talib, Zainal Abidin Zakaria, Azmi Ramizy, Asmiet Ahmed, Naser Mahmoud Paiman, Suriati Liew, Josephine Ying Chyi Muhd, Ibrahim B. Baqiah, Hussein Large-scale commercial production of nanoparticles via efficient, economical, and environmentally friendly methods is a challenging endeavour. The laser ablation method being a green and potential route of nanoparticles synthesis can be exploited to achieve this end. In this work, we report the ablation of a copper target submerged in distilled water by pulsed Nd:YAG laser. The influence of ablation time on the structure and optical properties of grown copper oxide nanoparticles are studied. Such nanoparticle composition and structure is determined by X-ray diffraction (XRD), Fourier transform infrared, and Raman analyses. Results from transmission electron microscopy images established that synthesised nanoparticles are a spherical shape with average sizes of 24–37 nm. Fluorescence spectra revealed the enhancement of nanoparticle concentration and reduction in the sizes with increasing ablation time, where the optimum ablation time is demonstrated to be 60 min. Photoluminescence spectra exhibited a prominent visible peak (green), which blueshifted from 542 to 537 nm, confirming the shrinkage of copper oxide particle size at higher ablation time. The XRD pattern showed that the prepared nanoparticles possess a single phase of monocline cupric oxide nanostructure. Springer 2018 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/69315/1/Impact%20of%20ablation%20time%20on%20Cu%20oxide%20nanoparticle%20green%20synthesis%20via%20pulsed%20laser%20ablation%20in%20liquid%20media.pdf Al-Jumaili, Batool Eneaze Bandar and Talib, Zainal Abidin and Zakaria, Azmi and Ramizy, Asmiet and Ahmed, Naser Mahmoud and Paiman, Suriati and Liew, Josephine Ying Chyi and Muhd, Ibrahim B. and Baqiah, Hussein (2018) Impact of ablation time on Cu oxide nanoparticle green synthesis via pulsed laser ablation in liquid media. Applied Physics A: Materials Science & Processing, 124 (9). art. no. 577. pp. 1-6. ISSN 0947-8396; ESSN: 1432-0630 https://link.springer.com/article/10.1007/s00339-018-1995-5 10.1007/s00339-018-1995-5
spellingShingle Al-Jumaili, Batool Eneaze Bandar
Talib, Zainal Abidin
Zakaria, Azmi
Ramizy, Asmiet
Ahmed, Naser Mahmoud
Paiman, Suriati
Liew, Josephine Ying Chyi
Muhd, Ibrahim B.
Baqiah, Hussein
Impact of ablation time on Cu oxide nanoparticle green synthesis via pulsed laser ablation in liquid media
title Impact of ablation time on Cu oxide nanoparticle green synthesis via pulsed laser ablation in liquid media
title_full Impact of ablation time on Cu oxide nanoparticle green synthesis via pulsed laser ablation in liquid media
title_fullStr Impact of ablation time on Cu oxide nanoparticle green synthesis via pulsed laser ablation in liquid media
title_full_unstemmed Impact of ablation time on Cu oxide nanoparticle green synthesis via pulsed laser ablation in liquid media
title_short Impact of ablation time on Cu oxide nanoparticle green synthesis via pulsed laser ablation in liquid media
title_sort impact of ablation time on cu oxide nanoparticle green synthesis via pulsed laser ablation in liquid media
url http://psasir.upm.edu.my/id/eprint/69315/
http://psasir.upm.edu.my/id/eprint/69315/
http://psasir.upm.edu.my/id/eprint/69315/
http://psasir.upm.edu.my/id/eprint/69315/1/Impact%20of%20ablation%20time%20on%20Cu%20oxide%20nanoparticle%20green%20synthesis%20via%20pulsed%20laser%20ablation%20in%20liquid%20media.pdf