Formation of a colloidal CdSe and ZnSe quantum dots via a gamma radiolytic technique

Colloidal cadmium selenide (CdSe) and zinc selenide (ZnSe) quantum dots with a hexagonal structure were synthesized by irradiating an aqueous solution containing metal precursors, poly (vinyl pyrrolidone), isopropyl alcohol, and organic solvents with 1.25-MeV gamma rays at a dose of 120 kGy. The rad...

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Main Authors: Salem, Aeshah Nizar, Saion, Elias, Al-Hada, Naif Mohammed, Shaari, Abdul Halim, Mohamed Kamari, Halimah, Soltani, Nayereh, Radiman, Shahidan
Format: Article
Language:English
Published: MDPI 2016
Online Access:http://psasir.upm.edu.my/id/eprint/52300/
http://psasir.upm.edu.my/id/eprint/52300/1/52300.pdf
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author Salem, Aeshah Nizar
Saion, Elias
Al-Hada, Naif Mohammed
Shaari, Abdul Halim
Mohamed Kamari, Halimah
Soltani, Nayereh
Radiman, Shahidan
author_facet Salem, Aeshah Nizar
Saion, Elias
Al-Hada, Naif Mohammed
Shaari, Abdul Halim
Mohamed Kamari, Halimah
Soltani, Nayereh
Radiman, Shahidan
author_sort Salem, Aeshah Nizar
building UPM Institutional Repository
collection Online Access
description Colloidal cadmium selenide (CdSe) and zinc selenide (ZnSe) quantum dots with a hexagonal structure were synthesized by irradiating an aqueous solution containing metal precursors, poly (vinyl pyrrolidone), isopropyl alcohol, and organic solvents with 1.25-MeV gamma rays at a dose of 120 kGy. The radiolytic processes occurring in water result in the nucleation of particles, which leads to the growth of the quantum dots. The physical properties of the CdSe and ZnSe nanoparticles were measured by various characterization techniques. X-ray diffraction (XRD) was used to confirm the nanocrystalline structure, energy-dispersive X-ray spectroscopy (EDX) was used to estimate the material composition of the samples, transmission electron microscopy (TEM) was used to determine the morphologies and average particle size distribution, and UV-visible spectroscopy was used to measure the optical absorption spectra, from which the band gap of the CdSe and ZnSe nanoparticles could be deduced.
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institution Universiti Putra Malaysia
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language English
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publishDate 2016
publisher MDPI
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spelling upm-523002017-06-05T05:41:54Z http://psasir.upm.edu.my/id/eprint/52300/ Formation of a colloidal CdSe and ZnSe quantum dots via a gamma radiolytic technique Salem, Aeshah Nizar Saion, Elias Al-Hada, Naif Mohammed Shaari, Abdul Halim Mohamed Kamari, Halimah Soltani, Nayereh Radiman, Shahidan Colloidal cadmium selenide (CdSe) and zinc selenide (ZnSe) quantum dots with a hexagonal structure were synthesized by irradiating an aqueous solution containing metal precursors, poly (vinyl pyrrolidone), isopropyl alcohol, and organic solvents with 1.25-MeV gamma rays at a dose of 120 kGy. The radiolytic processes occurring in water result in the nucleation of particles, which leads to the growth of the quantum dots. The physical properties of the CdSe and ZnSe nanoparticles were measured by various characterization techniques. X-ray diffraction (XRD) was used to confirm the nanocrystalline structure, energy-dispersive X-ray spectroscopy (EDX) was used to estimate the material composition of the samples, transmission electron microscopy (TEM) was used to determine the morphologies and average particle size distribution, and UV-visible spectroscopy was used to measure the optical absorption spectra, from which the band gap of the CdSe and ZnSe nanoparticles could be deduced. MDPI 2016 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/52300/1/52300.pdf Salem, Aeshah Nizar and Saion, Elias and Al-Hada, Naif Mohammed and Shaari, Abdul Halim and Mohamed Kamari, Halimah and Soltani, Nayereh and Radiman, Shahidan (2016) Formation of a colloidal CdSe and ZnSe quantum dots via a gamma radiolytic technique. Applied Sciences, 6 (10). art. no. 278. pp. 1-10. ISSN 2076-3417 http://www.mdpi.com/2076-3417/6/10/278 10.3390/app6100278
spellingShingle Salem, Aeshah Nizar
Saion, Elias
Al-Hada, Naif Mohammed
Shaari, Abdul Halim
Mohamed Kamari, Halimah
Soltani, Nayereh
Radiman, Shahidan
Formation of a colloidal CdSe and ZnSe quantum dots via a gamma radiolytic technique
title Formation of a colloidal CdSe and ZnSe quantum dots via a gamma radiolytic technique
title_full Formation of a colloidal CdSe and ZnSe quantum dots via a gamma radiolytic technique
title_fullStr Formation of a colloidal CdSe and ZnSe quantum dots via a gamma radiolytic technique
title_full_unstemmed Formation of a colloidal CdSe and ZnSe quantum dots via a gamma radiolytic technique
title_short Formation of a colloidal CdSe and ZnSe quantum dots via a gamma radiolytic technique
title_sort formation of a colloidal cdse and znse quantum dots via a gamma radiolytic technique
url http://psasir.upm.edu.my/id/eprint/52300/
http://psasir.upm.edu.my/id/eprint/52300/
http://psasir.upm.edu.my/id/eprint/52300/
http://psasir.upm.edu.my/id/eprint/52300/1/52300.pdf