Effect of PVA-co-MMA copolymer on the physical, mechanical, and thermal properties of tropical wood materials

The present study demonstrates the effect of copolymer on the physical, mechanical, and thermal properties of tropical wood and wood polymer composites (WPCs). Mixed monomers of methyl methacrylate (MMA) and polyvinyl alcohol (PVA) were effectively impregnated into the cellular structure of several...

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Main Authors: Islam, Md. Saiful, Hamdan, Sinin, Ahmad @ Ayob, Mansor, Hasan, Mahbub, Hassan, Azman, Mohamad Kassim, Mohamad Haafiz, Jawaid, Mohammad
Format: Article
Language:English
Published: Hindawi Publishing Corporation 2014
Online Access:http://psasir.upm.edu.my/id/eprint/37298/
http://psasir.upm.edu.my/id/eprint/37298/1/37298.pdf
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author Islam, Md. Saiful
Hamdan, Sinin
Ahmad @ Ayob, Mansor
Hasan, Mahbub
Hassan, Azman
Mohamad Kassim, Mohamad Haafiz
Jawaid, Mohammad
author_facet Islam, Md. Saiful
Hamdan, Sinin
Ahmad @ Ayob, Mansor
Hasan, Mahbub
Hassan, Azman
Mohamad Kassim, Mohamad Haafiz
Jawaid, Mohammad
author_sort Islam, Md. Saiful
building UPM Institutional Repository
collection Online Access
description The present study demonstrates the effect of copolymer on the physical, mechanical, and thermal properties of tropical wood and wood polymer composites (WPCs). Mixed monomers of methyl methacrylate (MMA) and polyvinyl alcohol (PVA) were effectively impregnated into the cellular structure of several types of tropical wood, which then underwent a catalyst-thermal process to polymerize and form WPC. The manufacturing of WPC was confirmed through Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopic (SEM) analysis. The SEM observation showed that polymer converted from monomers filled up wood cell cavities and tightly interacted with wood matrix. The X-ray diffraction results reveal that the degree of crystallinity was significantly improved upon impregnation with PVA-co-MMA copolymer. The modulus of elasticity (MOE) and compressive modulus were found to be significantly higher after treatment with MMA/PVA indicating improvement of mechanical properties of the wood samples. In addition, the modified WPC had lower water absorption compared to their corresponding raw samples. It is interesting to note that thermogravimetric (TGA) analysis shows an extensive improvement in thermal properties of WPC.
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spelling upm-372982018-10-11T03:01:59Z http://psasir.upm.edu.my/id/eprint/37298/ Effect of PVA-co-MMA copolymer on the physical, mechanical, and thermal properties of tropical wood materials Islam, Md. Saiful Hamdan, Sinin Ahmad @ Ayob, Mansor Hasan, Mahbub Hassan, Azman Mohamad Kassim, Mohamad Haafiz Jawaid, Mohammad The present study demonstrates the effect of copolymer on the physical, mechanical, and thermal properties of tropical wood and wood polymer composites (WPCs). Mixed monomers of methyl methacrylate (MMA) and polyvinyl alcohol (PVA) were effectively impregnated into the cellular structure of several types of tropical wood, which then underwent a catalyst-thermal process to polymerize and form WPC. The manufacturing of WPC was confirmed through Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopic (SEM) analysis. The SEM observation showed that polymer converted from monomers filled up wood cell cavities and tightly interacted with wood matrix. The X-ray diffraction results reveal that the degree of crystallinity was significantly improved upon impregnation with PVA-co-MMA copolymer. The modulus of elasticity (MOE) and compressive modulus were found to be significantly higher after treatment with MMA/PVA indicating improvement of mechanical properties of the wood samples. In addition, the modified WPC had lower water absorption compared to their corresponding raw samples. It is interesting to note that thermogravimetric (TGA) analysis shows an extensive improvement in thermal properties of WPC. Hindawi Publishing Corporation 2014 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/37298/1/37298.pdf Islam, Md. Saiful and Hamdan, Sinin and Ahmad @ Ayob, Mansor and Hasan, Mahbub and Hassan, Azman and Mohamad Kassim, Mohamad Haafiz and Jawaid, Mohammad (2014) Effect of PVA-co-MMA copolymer on the physical, mechanical, and thermal properties of tropical wood materials. Advances in Materials Science and Engineering, 2014. art. no. 626850. pp. 1-8. ISSN 1687-8434; ESSN: 1687-8442 http://www.hindawi.com/journals/amse/2014/626850/abs/ 10.1155/2014/626850
spellingShingle Islam, Md. Saiful
Hamdan, Sinin
Ahmad @ Ayob, Mansor
Hasan, Mahbub
Hassan, Azman
Mohamad Kassim, Mohamad Haafiz
Jawaid, Mohammad
Effect of PVA-co-MMA copolymer on the physical, mechanical, and thermal properties of tropical wood materials
title Effect of PVA-co-MMA copolymer on the physical, mechanical, and thermal properties of tropical wood materials
title_full Effect of PVA-co-MMA copolymer on the physical, mechanical, and thermal properties of tropical wood materials
title_fullStr Effect of PVA-co-MMA copolymer on the physical, mechanical, and thermal properties of tropical wood materials
title_full_unstemmed Effect of PVA-co-MMA copolymer on the physical, mechanical, and thermal properties of tropical wood materials
title_short Effect of PVA-co-MMA copolymer on the physical, mechanical, and thermal properties of tropical wood materials
title_sort effect of pva-co-mma copolymer on the physical, mechanical, and thermal properties of tropical wood materials
url http://psasir.upm.edu.my/id/eprint/37298/
http://psasir.upm.edu.my/id/eprint/37298/
http://psasir.upm.edu.my/id/eprint/37298/
http://psasir.upm.edu.my/id/eprint/37298/1/37298.pdf