Benzyl N-[(Z)-(1-methyl-2-sulfanylpropylidene)amino]carbamodithioate.
The title compound, C12H16N2S3, was obtained by the condensation reaction of S-benzyl dithiocarbazate and 3-mercaptobutan-2-one. The phenyl ring and thiol (SH) group are approximately perpendicular [S—C—C—C and N—C—C—S torsion angles = 67.8 (3) and 116.9 (2)°, respectively] to the rest of the mole...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English English |
| Published: |
International Union of Crystallography
2013
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| Online Access: | http://psasir.upm.edu.my/id/eprint/30000/ http://psasir.upm.edu.my/id/eprint/30000/1/Benzyl%20N.pdf |
| _version_ | 1848846555104149504 |
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| author | Break, Mohammed Khaled Mehta, Sachin M. Tahir, M. Ibrahim Crouse, Karen Anne Khoo, Teng Jin |
| author_facet | Break, Mohammed Khaled Mehta, Sachin M. Tahir, M. Ibrahim Crouse, Karen Anne Khoo, Teng Jin |
| author_sort | Break, Mohammed Khaled |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | The title compound, C12H16N2S3, was obtained by the condensation reaction of S-benzyl dithiocarbazate and 3-mercaptobutan-2-one. The phenyl ring and thiol (SH) group are approximately perpendicular [S—C—C—C and N—C—C—S torsion angles = 67.8 (3) and 116.9 (2)°, respectively] to the rest of the molecule. In the crystal, molecules are linked by weak S—H(...)S and N—H(...)S hydrogen bonds, π–π interactions between the benzene rings [centroid–centroid distance = 3.823 (2) Å] and C—H(...)π interactions. |
| first_indexed | 2025-11-15T09:04:34Z |
| format | Article |
| id | upm-30000 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T09:04:34Z |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-300002015-08-24T06:35:25Z http://psasir.upm.edu.my/id/eprint/30000/ Benzyl N-[(Z)-(1-methyl-2-sulfanylpropylidene)amino]carbamodithioate. Break, Mohammed Khaled Mehta, Sachin M. Tahir, M. Ibrahim Crouse, Karen Anne Khoo, Teng Jin The title compound, C12H16N2S3, was obtained by the condensation reaction of S-benzyl dithiocarbazate and 3-mercaptobutan-2-one. The phenyl ring and thiol (SH) group are approximately perpendicular [S—C—C—C and N—C—C—S torsion angles = 67.8 (3) and 116.9 (2)°, respectively] to the rest of the molecule. In the crystal, molecules are linked by weak S—H(...)S and N—H(...)S hydrogen bonds, π–π interactions between the benzene rings [centroid–centroid distance = 3.823 (2) Å] and C—H(...)π interactions. International Union of Crystallography 2013 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/30000/1/Benzyl%20N.pdf Break, Mohammed Khaled and Mehta, Sachin and M. Tahir, M. Ibrahim and Crouse, Karen Anne and Khoo, Teng Jin (2013) Benzyl N-[(Z)-(1-methyl-2-sulfanylpropylidene)amino]carbamodithioate. Acta Crystallographica Section E: Structure Reports Online, 69 (pt.2). p. 178. ISSN 1600-5368 10.1107/S1600536812051008 English |
| spellingShingle | Break, Mohammed Khaled Mehta, Sachin M. Tahir, M. Ibrahim Crouse, Karen Anne Khoo, Teng Jin Benzyl N-[(Z)-(1-methyl-2-sulfanylpropylidene)amino]carbamodithioate. |
| title | Benzyl N-[(Z)-(1-methyl-2-sulfanylpropylidene)amino]carbamodithioate. |
| title_full | Benzyl N-[(Z)-(1-methyl-2-sulfanylpropylidene)amino]carbamodithioate. |
| title_fullStr | Benzyl N-[(Z)-(1-methyl-2-sulfanylpropylidene)amino]carbamodithioate. |
| title_full_unstemmed | Benzyl N-[(Z)-(1-methyl-2-sulfanylpropylidene)amino]carbamodithioate. |
| title_short | Benzyl N-[(Z)-(1-methyl-2-sulfanylpropylidene)amino]carbamodithioate. |
| title_sort | benzyl n-[(z)-(1-methyl-2-sulfanylpropylidene)amino]carbamodithioate. |
| url | http://psasir.upm.edu.my/id/eprint/30000/ http://psasir.upm.edu.my/id/eprint/30000/ http://psasir.upm.edu.my/id/eprint/30000/1/Benzyl%20N.pdf |