Synthesis and characterization of ultra small PbS nanorods in sucrose ester microemulsion

In the present study, we report for the first time the synthesis of ultra small PbS nanorods in a non-ionic sugar based water-in-oil (w/o) microemulsion system using food grade sucrose ester as surfactant. PbS was formed by mixing lead nitrate and thioacetamide in the water core of the microemulsion...

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Main Authors: Huang, Nay Ming, Radiman, Shahidan, Lim, Hong Ngee, Yeong, S. K., Khiew, Poi Sim, Chiu, Wee Siong, Kong, S. N., Mohamed Saeed, G. H.
Format: Article
Language:English
Published: Elsevier 2009
Online Access:http://psasir.upm.edu.my/id/eprint/25254/
http://psasir.upm.edu.my/id/eprint/25254/1/Synthesis%20and%20characterization%20of%20ultra%20small%20PbS%20nanorods%20in%20sucrose%20ester%20microemulsion.pdf
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author Huang, Nay Ming
Radiman, Shahidan
Lim, Hong Ngee
Yeong, S. K.
Khiew, Poi Sim
Chiu, Wee Siong
Kong, S. N.
Mohamed Saeed, G. H.
author_facet Huang, Nay Ming
Radiman, Shahidan
Lim, Hong Ngee
Yeong, S. K.
Khiew, Poi Sim
Chiu, Wee Siong
Kong, S. N.
Mohamed Saeed, G. H.
author_sort Huang, Nay Ming
building UPM Institutional Repository
collection Online Access
description In the present study, we report for the first time the synthesis of ultra small PbS nanorods in a non-ionic sugar based water-in-oil (w/o) microemulsion system using food grade sucrose ester as surfactant. PbS was formed by mixing lead nitrate and thioacetamide in the water core of the microemulsion system. The as-prepared PbS nanorods were characterized by X-ray diffractometry (XRD), uv–visible absorption spectroscopy (UV–VIS), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). The diameter of the PbS nanorods were found to be extremely small, which is in the range of 2.64 nm to 2.91 nm depending on reaction aging time. Spherical PbS nanoparticles were formed after 12 h and PbS nanorods were formed after more than 1 day of reaction aging time.
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institution Universiti Putra Malaysia
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language English
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spelling upm-252542016-03-21T09:52:20Z http://psasir.upm.edu.my/id/eprint/25254/ Synthesis and characterization of ultra small PbS nanorods in sucrose ester microemulsion Huang, Nay Ming Radiman, Shahidan Lim, Hong Ngee Yeong, S. K. Khiew, Poi Sim Chiu, Wee Siong Kong, S. N. Mohamed Saeed, G. H. In the present study, we report for the first time the synthesis of ultra small PbS nanorods in a non-ionic sugar based water-in-oil (w/o) microemulsion system using food grade sucrose ester as surfactant. PbS was formed by mixing lead nitrate and thioacetamide in the water core of the microemulsion system. The as-prepared PbS nanorods were characterized by X-ray diffractometry (XRD), uv–visible absorption spectroscopy (UV–VIS), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). The diameter of the PbS nanorods were found to be extremely small, which is in the range of 2.64 nm to 2.91 nm depending on reaction aging time. Spherical PbS nanoparticles were formed after 12 h and PbS nanorods were formed after more than 1 day of reaction aging time. Elsevier 2009-02-15 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/25254/1/Synthesis%20and%20characterization%20of%20ultra%20small%20PbS%20nanorods%20in%20sucrose%20ester%20microemulsion.pdf Huang, Nay Ming and Radiman, Shahidan and Lim, Hong Ngee and Yeong, S. K. and Khiew, Poi Sim and Chiu, Wee Siong and Kong, S. N. and Mohamed Saeed, G. H. (2009) Synthesis and characterization of ultra small PbS nanorods in sucrose ester microemulsion. Materials Letters, 63 (3-4). pp. 500-503. ISSN 0167-577X; ESSN: 1873-4979 10.1016/j.matlet.2008.11.034
spellingShingle Huang, Nay Ming
Radiman, Shahidan
Lim, Hong Ngee
Yeong, S. K.
Khiew, Poi Sim
Chiu, Wee Siong
Kong, S. N.
Mohamed Saeed, G. H.
Synthesis and characterization of ultra small PbS nanorods in sucrose ester microemulsion
title Synthesis and characterization of ultra small PbS nanorods in sucrose ester microemulsion
title_full Synthesis and characterization of ultra small PbS nanorods in sucrose ester microemulsion
title_fullStr Synthesis and characterization of ultra small PbS nanorods in sucrose ester microemulsion
title_full_unstemmed Synthesis and characterization of ultra small PbS nanorods in sucrose ester microemulsion
title_short Synthesis and characterization of ultra small PbS nanorods in sucrose ester microemulsion
title_sort synthesis and characterization of ultra small pbs nanorods in sucrose ester microemulsion
url http://psasir.upm.edu.my/id/eprint/25254/
http://psasir.upm.edu.my/id/eprint/25254/
http://psasir.upm.edu.my/id/eprint/25254/1/Synthesis%20and%20characterization%20of%20ultra%20small%20PbS%20nanorods%20in%20sucrose%20ester%20microemulsion.pdf