(2,2'-Bipyridyl-[kappa]2N,N')bis(N-butyl-N-methyldithiocarbamato-[kappa]2S,S')cadmium(II).
The CdII atom in the title compound, [Cd(C6H12NS2)2(C10H8N2)], is hexacoordinated by two dithiocarbamate ligands and the N atoms from a bidentate 2,2'-bipyridyl molecule. The coordination geometry is based on a distorted trigonal-prismatic arrangement of the N2S4 donor set. Supramolecular chain...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English English |
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International Union of Crystallography
2011
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| Online Access: | http://psasir.upm.edu.my/id/eprint/24787/ http://psasir.upm.edu.my/id/eprint/24787/1/2.pdf |
| _version_ | 1848845131713609728 |
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| author | Jamaluddin, Nur Amirah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. |
| author_facet | Jamaluddin, Nur Amirah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. |
| author_sort | Jamaluddin, Nur Amirah |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | The CdII atom in the title compound, [Cd(C6H12NS2)2(C10H8N2)], is hexacoordinated by two dithiocarbamate ligands and the N atoms from a bidentate 2,2'-bipyridyl molecule. The coordination geometry is based on a distorted trigonal-prismatic arrangement of the N2S4 donor set. Supramolecular chains, aligned along the a-axis direction, are mediated by C-H...S interactions and these are connected into layers that stack along the c axis via [pi]-[pi] interactions [Cg(pyridyl)...Cg(pyridyl) = 3.6587 (13) Å]. |
| first_indexed | 2025-11-15T08:41:57Z |
| format | Article |
| id | upm-24787 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T08:41:57Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-247872015-10-06T04:07:38Z http://psasir.upm.edu.my/id/eprint/24787/ (2,2'-Bipyridyl-[kappa]2N,N')bis(N-butyl-N-methyldithiocarbamato-[kappa]2S,S')cadmium(II). Jamaluddin, Nur Amirah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. The CdII atom in the title compound, [Cd(C6H12NS2)2(C10H8N2)], is hexacoordinated by two dithiocarbamate ligands and the N atoms from a bidentate 2,2'-bipyridyl molecule. The coordination geometry is based on a distorted trigonal-prismatic arrangement of the N2S4 donor set. Supramolecular chains, aligned along the a-axis direction, are mediated by C-H...S interactions and these are connected into layers that stack along the c axis via [pi]-[pi] interactions [Cg(pyridyl)...Cg(pyridyl) = 3.6587 (13) Å]. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/24787/1/2.pdf Jamaluddin, Nur Amirah and Baba, Ibrahim and Mohamed Tahir, Mohamed Ibrahim and Tiekink, Edward R. T. (2011) (2,2'-Bipyridyl-[kappa]2N,N')bis(N-butyl-N-methyldithiocarbamato-[kappa]2S,S')cadmium(II). Acta Crystallographica Section E: Structure Reports Online, 67. pp. 384-385. ISSN 1600-5368 10.1107/S1600536811006878 English |
| spellingShingle | Jamaluddin, Nur Amirah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. (2,2'-Bipyridyl-[kappa]2N,N')bis(N-butyl-N-methyldithiocarbamato-[kappa]2S,S')cadmium(II). |
| title | (2,2'-Bipyridyl-[kappa]2N,N')bis(N-butyl-N-methyldithiocarbamato-[kappa]2S,S')cadmium(II). |
| title_full | (2,2'-Bipyridyl-[kappa]2N,N')bis(N-butyl-N-methyldithiocarbamato-[kappa]2S,S')cadmium(II). |
| title_fullStr | (2,2'-Bipyridyl-[kappa]2N,N')bis(N-butyl-N-methyldithiocarbamato-[kappa]2S,S')cadmium(II). |
| title_full_unstemmed | (2,2'-Bipyridyl-[kappa]2N,N')bis(N-butyl-N-methyldithiocarbamato-[kappa]2S,S')cadmium(II). |
| title_short | (2,2'-Bipyridyl-[kappa]2N,N')bis(N-butyl-N-methyldithiocarbamato-[kappa]2S,S')cadmium(II). |
| title_sort | (2,2'-bipyridyl-[kappa]2n,n')bis(n-butyl-n-methyldithiocarbamato-[kappa]2s,s')cadmium(ii). |
| url | http://psasir.upm.edu.my/id/eprint/24787/ http://psasir.upm.edu.my/id/eprint/24787/ http://psasir.upm.edu.my/id/eprint/24787/1/2.pdf |