Thermal and dynamic mechanical behavior of cellulose- and Oil Palm Empty Fruit Bunch (OPEFB)-filled polypropylene biocomposites.

This paper presents a comparative study on the effect of cellulose and oil palm empty fruit bunch (OPEFB) on thermal degradation and dynamic mechanical properties of polypropylene (PP) biocomposite. Thermogravimetric analysis (TGA) of the biocomposite showed decrease in thermal stability and degrada...

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Main Authors: Khalid , M., Ratnam , Chantara Thevy, Abdullah, Luqman Chuah, Ali , Salmiaton, Choong, Thomas Shean Yaw, Jalaludin, H.
Format: Article
Language:English
English
Published: Taylor & Francis 2009
Online Access:http://psasir.upm.edu.my/id/eprint/17379/
http://psasir.upm.edu.my/id/eprint/17379/1/Thermal%20and%20dynamic%20mechanical%20behavior%20of%20cellulose.pdf
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author Khalid , M.
Ratnam , Chantara Thevy
Abdullah, Luqman Chuah
Ali , Salmiaton
Choong, Thomas Shean Yaw
Jalaludin, H.
author_facet Khalid , M.
Ratnam , Chantara Thevy
Abdullah, Luqman Chuah
Ali , Salmiaton
Choong, Thomas Shean Yaw
Jalaludin, H.
author_sort Khalid , M.
building UPM Institutional Repository
collection Online Access
description This paper presents a comparative study on the effect of cellulose and oil palm empty fruit bunch (OPEFB) on thermal degradation and dynamic mechanical properties of polypropylene (PP) biocomposite. Thermogravimetric analysis (TGA) of the biocomposite showed decrease in thermal stability and degradation temperature and increase in ash content. This was a result of lower thermal stability of the biofiller compared of that of the PP. However, an improvement was observed in the thermal properties of PP-cellulose biocomposite due to the dispersion and interfacial adhesion between the cellulose and PP. The glass transition temperatures (Tg) of the biocomposites were not significantly changed. The storage modulus (E′) of the biocomposites was found to be higher than that of pure PP, because incorporation of biofiller increased the stiffness of the biocomposites. The decline in E″ of the biocomposites at higher temperatures is associated with the increasing viscosity and chain mobility of matrix polymer.
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publishDate 2009
publisher Taylor & Francis
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spelling upm-173792015-09-28T03:18:37Z http://psasir.upm.edu.my/id/eprint/17379/ Thermal and dynamic mechanical behavior of cellulose- and Oil Palm Empty Fruit Bunch (OPEFB)-filled polypropylene biocomposites. Khalid , M. Ratnam , Chantara Thevy Abdullah, Luqman Chuah Ali , Salmiaton Choong, Thomas Shean Yaw Jalaludin, H. This paper presents a comparative study on the effect of cellulose and oil palm empty fruit bunch (OPEFB) on thermal degradation and dynamic mechanical properties of polypropylene (PP) biocomposite. Thermogravimetric analysis (TGA) of the biocomposite showed decrease in thermal stability and degradation temperature and increase in ash content. This was a result of lower thermal stability of the biofiller compared of that of the PP. However, an improvement was observed in the thermal properties of PP-cellulose biocomposite due to the dispersion and interfacial adhesion between the cellulose and PP. The glass transition temperatures (Tg) of the biocomposites were not significantly changed. The storage modulus (E′) of the biocomposites was found to be higher than that of pure PP, because incorporation of biofiller increased the stiffness of the biocomposites. The decline in E″ of the biocomposites at higher temperatures is associated with the increasing viscosity and chain mobility of matrix polymer. Taylor & Francis 2009 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/17379/1/Thermal%20and%20dynamic%20mechanical%20behavior%20of%20cellulose.pdf Khalid , M. and Ratnam , Chantara Thevy and Abdullah, Luqman Chuah and Ali , Salmiaton and Choong, Thomas Shean Yaw and Jalaludin, H. (2009) Thermal and dynamic mechanical behavior of cellulose- and Oil Palm Empty Fruit Bunch (OPEFB)-filled polypropylene biocomposites. Polymer-Plastics Technology and Engineering, 48 (12). pp. 1244-1251. ISSN 0360-2559 10.1080/03602550903282986 English
spellingShingle Khalid , M.
Ratnam , Chantara Thevy
Abdullah, Luqman Chuah
Ali , Salmiaton
Choong, Thomas Shean Yaw
Jalaludin, H.
Thermal and dynamic mechanical behavior of cellulose- and Oil Palm Empty Fruit Bunch (OPEFB)-filled polypropylene biocomposites.
title Thermal and dynamic mechanical behavior of cellulose- and Oil Palm Empty Fruit Bunch (OPEFB)-filled polypropylene biocomposites.
title_full Thermal and dynamic mechanical behavior of cellulose- and Oil Palm Empty Fruit Bunch (OPEFB)-filled polypropylene biocomposites.
title_fullStr Thermal and dynamic mechanical behavior of cellulose- and Oil Palm Empty Fruit Bunch (OPEFB)-filled polypropylene biocomposites.
title_full_unstemmed Thermal and dynamic mechanical behavior of cellulose- and Oil Palm Empty Fruit Bunch (OPEFB)-filled polypropylene biocomposites.
title_short Thermal and dynamic mechanical behavior of cellulose- and Oil Palm Empty Fruit Bunch (OPEFB)-filled polypropylene biocomposites.
title_sort thermal and dynamic mechanical behavior of cellulose- and oil palm empty fruit bunch (opefb)-filled polypropylene biocomposites.
url http://psasir.upm.edu.my/id/eprint/17379/
http://psasir.upm.edu.my/id/eprint/17379/
http://psasir.upm.edu.my/id/eprint/17379/1/Thermal%20and%20dynamic%20mechanical%20behavior%20of%20cellulose.pdf