Synthesis, characterization and optimum reaction conditions of fatty hydrazide from triacylglycerides

Fatty Hydrazide (FH) has been synthesized via reaction of palm olein with hydrazine hydrate by reflux and characterized using spectroscopic methods and CHN analyzer. Optimum reaction conditions were studied in order to optimize the reaction time and hydrazine hydrate/palm olein ratio. When the hydra...

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Main Authors: Al-Mulla, Emad A. Jaffar, Wan Yunus, Wan Md. Zin, Ibrahim, Nor Azowa, Ab. Rahman, Mohamad Zaki
Format: Article
Language:English
English
Published: Medwell Publishing 2008
Subjects:
Online Access:http://psasir.upm.edu.my/id/eprint/16955/
http://psasir.upm.edu.my/id/eprint/16955/1/Synthesis%2C%20characterization%20and%20potimum%20reaction.pdf
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author Al-Mulla, Emad A. Jaffar
Wan Yunus, Wan Md. Zin
Ibrahim, Nor Azowa
Ab. Rahman, Mohamad Zaki
author_facet Al-Mulla, Emad A. Jaffar
Wan Yunus, Wan Md. Zin
Ibrahim, Nor Azowa
Ab. Rahman, Mohamad Zaki
author_sort Al-Mulla, Emad A. Jaffar
building UPM Institutional Repository
collection Online Access
description Fatty Hydrazide (FH) has been synthesized via reaction of palm olein with hydrazine hydrate by reflux and characterized using spectroscopic methods and CHN analyzer. Optimum reaction conditions were studied in order to optimize the reaction time and hydrazine hydrate/palm olein ratio. When the hydrazinolysis reaction was carried out 7:1 molar ratio of hydrazine hydrate to palm olein, the conversion of palm olein was 82% and the maximum of conversion to FH was 84% when the reaction time was 12 h. FH was also prepared from palm stearin and corn oil and then, the conversion percentages of these oils into their fatty hydrazides were investigated to compare with palm olein.
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language English
English
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publishDate 2008
publisher Medwell Publishing
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spelling upm-169552015-12-04T09:04:30Z http://psasir.upm.edu.my/id/eprint/16955/ Synthesis, characterization and optimum reaction conditions of fatty hydrazide from triacylglycerides Al-Mulla, Emad A. Jaffar Wan Yunus, Wan Md. Zin Ibrahim, Nor Azowa Ab. Rahman, Mohamad Zaki Fatty Hydrazide (FH) has been synthesized via reaction of palm olein with hydrazine hydrate by reflux and characterized using spectroscopic methods and CHN analyzer. Optimum reaction conditions were studied in order to optimize the reaction time and hydrazine hydrate/palm olein ratio. When the hydrazinolysis reaction was carried out 7:1 molar ratio of hydrazine hydrate to palm olein, the conversion of palm olein was 82% and the maximum of conversion to FH was 84% when the reaction time was 12 h. FH was also prepared from palm stearin and corn oil and then, the conversion percentages of these oils into their fatty hydrazides were investigated to compare with palm olein. Medwell Publishing 2008 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/16955/1/Synthesis%2C%20characterization%20and%20potimum%20reaction.pdf Al-Mulla, Emad A. Jaffar and Wan Yunus, Wan Md. Zin and Ibrahim, Nor Azowa and Ab. Rahman, Mohamad Zaki (2008) Synthesis, characterization and optimum reaction conditions of fatty hydrazide from triacylglycerides. Research Journal of Applied Sciences, 8 (3). pp. 545-549. ISSN 1815-932X Hydrazines - Synthesis Oils and fats - Analysis Stearin - Analysis English
spellingShingle Hydrazines - Synthesis
Oils and fats - Analysis
Stearin - Analysis
Al-Mulla, Emad A. Jaffar
Wan Yunus, Wan Md. Zin
Ibrahim, Nor Azowa
Ab. Rahman, Mohamad Zaki
Synthesis, characterization and optimum reaction conditions of fatty hydrazide from triacylglycerides
title Synthesis, characterization and optimum reaction conditions of fatty hydrazide from triacylglycerides
title_full Synthesis, characterization and optimum reaction conditions of fatty hydrazide from triacylglycerides
title_fullStr Synthesis, characterization and optimum reaction conditions of fatty hydrazide from triacylglycerides
title_full_unstemmed Synthesis, characterization and optimum reaction conditions of fatty hydrazide from triacylglycerides
title_short Synthesis, characterization and optimum reaction conditions of fatty hydrazide from triacylglycerides
title_sort synthesis, characterization and optimum reaction conditions of fatty hydrazide from triacylglycerides
topic Hydrazines - Synthesis
Oils and fats - Analysis
Stearin - Analysis
url http://psasir.upm.edu.my/id/eprint/16955/
http://psasir.upm.edu.my/id/eprint/16955/1/Synthesis%2C%20characterization%20and%20potimum%20reaction.pdf