Thermal degradation of (zinc-aluminium-layered double hydroxide-dioctyl sulphosuccinate) nanocomposite

Zinc-aluminium-layered double hydroxide containing dioctyl sulphosuccinate in the lamella for the formation of an organic-inorganic layered hybrid nanocomposite (ZALDIN) was synthesized by spontaneous self-assembly of organic and inorganic components from an aqueous phase. The heat-treated ZALDIN (Z...

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Main Authors: Hussein, Mohd Zobir, Yun-Hin, Taufiq-Yap, Tawang, Mohd Maulana, Shahadan, Rodhyrolin
Format: Article
Language:English
Published: Elsevier Science 2002
Online Access:http://psasir.upm.edu.my/id/eprint/116768/
http://psasir.upm.edu.my/id/eprint/116768/2/116768.pdf
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author Hussein, Mohd Zobir
Yun-Hin, Taufiq-Yap
Tawang, Mohd Maulana
Shahadan, Rodhyrolin
author_facet Hussein, Mohd Zobir
Yun-Hin, Taufiq-Yap
Tawang, Mohd Maulana
Shahadan, Rodhyrolin
author_sort Hussein, Mohd Zobir
building UPM Institutional Repository
collection Online Access
description Zinc-aluminium-layered double hydroxide containing dioctyl sulphosuccinate in the lamella for the formation of an organic-inorganic layered hybrid nanocomposite (ZALDIN) was synthesized by spontaneous self-assembly of organic and inorganic components from an aqueous phase. The heat-treated ZALDIN (ZALDITs) was obtained by heating ZALDIN at 150-800 °C under atmospheric pressure. The layered structure of the nanocomposite collapsed when the sample was heated at 150-250 °C. The formation of ZnO phase was observed when ZALDIN was heat-treated at 250 °C or higher, and in addition, a ZnS phase was also observed when the sample was heat-treated at 800 °C. The ZnO phase became more prominent as the heating temperature increased. The specific surface area for ZALDITs generally increased with temperature, with an optimum of about 62 m2/g at 600 °C. However, the surface area decreased to 39 m2/g at 800 °C, compared to 4 m2/g for ZALDIN.
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spelling upm-1167682025-07-07T03:50:23Z http://psasir.upm.edu.my/id/eprint/116768/ Thermal degradation of (zinc-aluminium-layered double hydroxide-dioctyl sulphosuccinate) nanocomposite Hussein, Mohd Zobir Yun-Hin, Taufiq-Yap Tawang, Mohd Maulana Shahadan, Rodhyrolin Zinc-aluminium-layered double hydroxide containing dioctyl sulphosuccinate in the lamella for the formation of an organic-inorganic layered hybrid nanocomposite (ZALDIN) was synthesized by spontaneous self-assembly of organic and inorganic components from an aqueous phase. The heat-treated ZALDIN (ZALDITs) was obtained by heating ZALDIN at 150-800 °C under atmospheric pressure. The layered structure of the nanocomposite collapsed when the sample was heated at 150-250 °C. The formation of ZnO phase was observed when ZALDIN was heat-treated at 250 °C or higher, and in addition, a ZnS phase was also observed when the sample was heat-treated at 800 °C. The ZnO phase became more prominent as the heating temperature increased. The specific surface area for ZALDITs generally increased with temperature, with an optimum of about 62 m2/g at 600 °C. However, the surface area decreased to 39 m2/g at 800 °C, compared to 4 m2/g for ZALDIN. Elsevier Science 2002 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/116768/2/116768.pdf Hussein, Mohd Zobir and Yun-Hin, Taufiq-Yap and Tawang, Mohd Maulana and Shahadan, Rodhyrolin (2002) Thermal degradation of (zinc-aluminium-layered double hydroxide-dioctyl sulphosuccinate) nanocomposite. Materials Chemistry and Physics, 74 (3). pp. 265-271. ISSN 0254-0584 https://linkinghub.elsevier.com/retrieve/pii/S0254058401004813 10.1016/S0254-0584(01)00481-3
spellingShingle Hussein, Mohd Zobir
Yun-Hin, Taufiq-Yap
Tawang, Mohd Maulana
Shahadan, Rodhyrolin
Thermal degradation of (zinc-aluminium-layered double hydroxide-dioctyl sulphosuccinate) nanocomposite
title Thermal degradation of (zinc-aluminium-layered double hydroxide-dioctyl sulphosuccinate) nanocomposite
title_full Thermal degradation of (zinc-aluminium-layered double hydroxide-dioctyl sulphosuccinate) nanocomposite
title_fullStr Thermal degradation of (zinc-aluminium-layered double hydroxide-dioctyl sulphosuccinate) nanocomposite
title_full_unstemmed Thermal degradation of (zinc-aluminium-layered double hydroxide-dioctyl sulphosuccinate) nanocomposite
title_short Thermal degradation of (zinc-aluminium-layered double hydroxide-dioctyl sulphosuccinate) nanocomposite
title_sort thermal degradation of (zinc-aluminium-layered double hydroxide-dioctyl sulphosuccinate) nanocomposite
url http://psasir.upm.edu.my/id/eprint/116768/
http://psasir.upm.edu.my/id/eprint/116768/
http://psasir.upm.edu.my/id/eprint/116768/
http://psasir.upm.edu.my/id/eprint/116768/2/116768.pdf