Voltammetric oxidation of solution and solid phases of salts of [V(CO)6]- in aqueous (electrolyte) media

Voltammetric oxidation of solution and solid phases of salts of [V(CO)6]- in aqueous (electrolyte) media

In the absence of water and oxygen the solution phase voltammetry of [V(CO)6]- in organic solvents exhibits an extremely well-defined, reversible, one-electron redox couple [V(CO)6]- ⇋ V(CO)6 + e-; ET1/2 = -0.35 V versus the ferrocenium/ferrocene (Fc+/Fc) couple, where ET1/2 is the reversible half-w...

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Bibliographic Details
Main Authors: Bond, Alan M., Colton, Ray, Mahon, Peter J., Snook, Graeme A., Tan, Wee T.
Format: Article
Published: American Chemical Societyservice@acs.org 1998
Online Access:http://psasir.upm.edu.my/id/eprint/116173/

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