Voltammetric oxidation of solution and solid phases of salts of [V(CO)6]- in aqueous (electrolyte) media
In the absence of water and oxygen the solution phase voltammetry of [V(CO)6]- in organic solvents exhibits an extremely well-defined, reversible, one-electron redox couple [V(CO)6]- ⇋ V(CO)6 + e-; ET1/2 = -0.35 V versus the ferrocenium/ferrocene (Fc+/Fc) couple, where ET1/2 is the reversible half-w...
| Main Authors: | , , , , |
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| Format: | Article |
| Published: |
American Chemical Societyservice@acs.org
1998
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| Online Access: | http://psasir.upm.edu.my/id/eprint/116173/ |