Development of porous MIL-101 derived catalyst application for green diesel production
A novel three-dimensional MIL-101 derived porous carbon-based Ni-doped catalyst was synthesised via slow pyrolysis of Ni/MIL-101(Cr) precursor at 600 °C for 4 h. The catalytic activities were evaluated via one-pot hydrodeoxygenation (HDO) reactions by using palmitic acid (PA) as a model compound to...
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| Format: | Article |
| Language: | English |
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Elsevier
2023
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| Online Access: | http://psasir.upm.edu.my/id/eprint/111492/ http://psasir.upm.edu.my/id/eprint/111492/1/Development%20of%20porous%20MIL-101%20derived%20c...pdf |
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| author | Chang, He Seenivasagam, Sivasangar Taufiq Yap, Yun Hin Saiman, Mohd Izham Ghassan, Abdulkareem-Alsultan |
| author_facet | Chang, He Seenivasagam, Sivasangar Taufiq Yap, Yun Hin Saiman, Mohd Izham Ghassan, Abdulkareem-Alsultan |
| author_sort | Chang, He |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | A novel three-dimensional MIL-101 derived porous carbon-based Ni-doped catalyst was synthesised via slow pyrolysis of Ni/MIL-101(Cr) precursor at 600 °C for 4 h. The catalytic activities were evaluated via one-pot hydrodeoxygenation (HDO) reactions by using palmitic acid (PA) as a model compound to produce green diesel within the range of a paraffinic hydrocarbon. The results show that Ni/P-MIL-101 exhibited excellent catalytic activity and recyclability in the HDO reaction of PA at a reaction temperature of 400 °C for 3 h under 3 MPa purified H2 pressure with 5 wt% catalyst loading. The conversion of PA and hydrocarbon selectivity were found to be 100 % with Ni loading > 8 wt% on P-MIL-101. In addition, both 25 and 14 wt% Ni/P-MIL-101 catalysts were able to recycle up to 7 and 15 times, respectively, and nearly 100 % alkane yield was achieved. The unique properties of Ni/P-MIL-101 catalyst such as finely dispersed added Ni, abundant acid and basic sites, and the presence of Cr2O3 active sites from pyrolysed MIL-101 with its mesoporous structures play a synergetic role in obtaining a very efficient catalyst for hydrodeoxygenation reaction. It is worth mentioning that the catalyst has an excellent catalytic effect on different kinds of fatty acid (ester) raw materials. Therefore, this Ni/P-MIL-101 catalyst has good prospects and potential for industrial application in green diesel production. |
| first_indexed | 2025-11-15T14:08:54Z |
| format | Article |
| id | upm-111492 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T14:08:54Z |
| publishDate | 2023 |
| publisher | Elsevier |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-1114922024-08-19T02:24:56Z http://psasir.upm.edu.my/id/eprint/111492/ Development of porous MIL-101 derived catalyst application for green diesel production Chang, He Seenivasagam, Sivasangar Taufiq Yap, Yun Hin Saiman, Mohd Izham Ghassan, Abdulkareem-Alsultan A novel three-dimensional MIL-101 derived porous carbon-based Ni-doped catalyst was synthesised via slow pyrolysis of Ni/MIL-101(Cr) precursor at 600 °C for 4 h. The catalytic activities were evaluated via one-pot hydrodeoxygenation (HDO) reactions by using palmitic acid (PA) as a model compound to produce green diesel within the range of a paraffinic hydrocarbon. The results show that Ni/P-MIL-101 exhibited excellent catalytic activity and recyclability in the HDO reaction of PA at a reaction temperature of 400 °C for 3 h under 3 MPa purified H2 pressure with 5 wt% catalyst loading. The conversion of PA and hydrocarbon selectivity were found to be 100 % with Ni loading > 8 wt% on P-MIL-101. In addition, both 25 and 14 wt% Ni/P-MIL-101 catalysts were able to recycle up to 7 and 15 times, respectively, and nearly 100 % alkane yield was achieved. The unique properties of Ni/P-MIL-101 catalyst such as finely dispersed added Ni, abundant acid and basic sites, and the presence of Cr2O3 active sites from pyrolysed MIL-101 with its mesoporous structures play a synergetic role in obtaining a very efficient catalyst for hydrodeoxygenation reaction. It is worth mentioning that the catalyst has an excellent catalytic effect on different kinds of fatty acid (ester) raw materials. Therefore, this Ni/P-MIL-101 catalyst has good prospects and potential for industrial application in green diesel production. Elsevier 2023 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/111492/1/Development%20of%20porous%20MIL-101%20derived%20c...pdf Chang, He and Seenivasagam, Sivasangar and Taufiq Yap, Yun Hin and Saiman, Mohd Izham and Ghassan, Abdulkareem-Alsultan (2023) Development of porous MIL-101 derived catalyst application for green diesel production. Fuel, 355. art. no. 129459. pp. 1-21. ISSN 0016-2361 https://www.sciencedirect.com/science/article/pii/S0016236123020732 Biofuel 10.1016/j.fuel.2023.129459 |
| spellingShingle | Biofuel Chang, He Seenivasagam, Sivasangar Taufiq Yap, Yun Hin Saiman, Mohd Izham Ghassan, Abdulkareem-Alsultan Development of porous MIL-101 derived catalyst application for green diesel production |
| title | Development of porous MIL-101 derived catalyst application for green diesel production |
| title_full | Development of porous MIL-101 derived catalyst application for green diesel production |
| title_fullStr | Development of porous MIL-101 derived catalyst application for green diesel production |
| title_full_unstemmed | Development of porous MIL-101 derived catalyst application for green diesel production |
| title_short | Development of porous MIL-101 derived catalyst application for green diesel production |
| title_sort | development of porous mil-101 derived catalyst application for green diesel production |
| topic | Biofuel |
| url | http://psasir.upm.edu.my/id/eprint/111492/ http://psasir.upm.edu.my/id/eprint/111492/ http://psasir.upm.edu.my/id/eprint/111492/ http://psasir.upm.edu.my/id/eprint/111492/1/Development%20of%20porous%20MIL-101%20derived%20c...pdf |