Oxidative addition of (bromoethynyl)benzene to κ2- acetylacetonatobis(trimethylphosphine)rhodium(I)

Oxidative addition of (bromoethynyl)benzene to κ2- acetylacetonatobis(trimethylphosphine)rhodium(I)

The reaction of (bromoethynyl)benzene with κ2-acetylacetonatobis(trimethylphosphine)rhodium(I), [Rh(acac)(PMe3)2] 1, was followed by in situ1H and 31P NMR spectroscopy. The kinetic product is that of cis-oxidative addition of the C–Br bond to Rh, and this species rearranges to the thermodynamically...

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Bibliographic Details
Main Authors: Marie-Hélène, Thibault, Tay, Meng Guan, Andrei S, Batsanov, Judith AK, Howard, Todd B, Marder
Format: Article
Language:English
Published: Elsevier 2013
Subjects:
QC Physics
QD Chemistry
Online Access:http://ir.unimas.my/id/eprint/7404/
http://ir.unimas.my/id/eprint/7404/1/Oxidative%20addition%20of%20%28bromoethynyl%29benzene%20to%202-acetylacetonato%20bis%28trimethylphosphine%29%20rhodium%28I%29%20-%20%28abstract%29.pdf

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http://ir.unimas.my/id/eprint/7404/
http://ir.unimas.my/id/eprint/7404/1/Oxidative%20addition%20of%20%28bromoethynyl%29benzene%20to%202-acetylacetonato%20bis%28trimethylphosphine%29%20rhodium%28I%29%20-%20%28abstract%29.pdf

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