Regiospecific Formation and Unusual Optical Properties of 2, 5‐Bis (arylethynyl) rhodacyclopentadienes: A New Class of Luminescent Organometallics

A series of 2,5-bis(arylethynyl)rhodacyclopentadienes has been prepared by a rare example of regiospecific reductive coupling of 1,4-(p-R-phenyl)-1,3-butadiynes (R[DOUBLE BOND]H, Me, OMe, SMe, NMe2, CF3, CO2Me, CN, NO2, −C[TRIPLE BOND]C-(p-C6H4[BOND]NHex2), −C[TRIPLE BOND]C[BOND](p-C6H4[BOND]CO2Oct)...

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Bibliographic Details
Main Authors: Andreas, Steffen, Richard M, Ward, Meng Guan, Tay, Robert M, Edkins, Fabian, Seeler, Magda van, Leeuwen, Lars‐Olof, Pålsson, Andrew, Beeby, Andrei S, Batsanov, Judith AK, Howard, Todd B, Marder
Format: Article
Published: WILEY‐VCH Verlag 2014
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Online Access:http://ir.unimas.my/id/eprint/7401/