Visible-driven industrial wastewater remediation using black titania: optimization, energy consumption, treatment, and material preparation costs estimation

Herein, black titania nanoparticles (BTNs) were synthesized via chloride sol–gel route which were then employed for the remediation of phenolic compounds (PCs) contaminated wastewater. A total of 2.70 L of input reagents and 28.33 kWh of electrical energy (EE) were required to produce 1 kilogramme o...

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Main Authors: Nawaz, Rab, Arshad, Ushtar, Marlia, Mohd Hanafiah, Haider, Sajjad, Anjum, Muzammil, Abdel Baki, Zaher, Khan, Rawaiz, Zaini, Sakawi, Muhammad, Aqif, Haider, Adnan, Sumaiya, Zainal Abidin
Format: Article
Language:English
Published: Elsevier 2025
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/44416/
http://umpir.ump.edu.my/id/eprint/44416/1/Visible-driven%20industrial%20wastewater%20remediation%20using%20black%20titania.pdf
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author Nawaz, Rab
Arshad, Ushtar
Marlia, Mohd Hanafiah
Haider, Sajjad
Anjum, Muzammil
Abdel Baki, Zaher
Khan, Rawaiz
Zaini, Sakawi
Muhammad, Aqif
Haider, Adnan
Sumaiya, Zainal Abidin
author_facet Nawaz, Rab
Arshad, Ushtar
Marlia, Mohd Hanafiah
Haider, Sajjad
Anjum, Muzammil
Abdel Baki, Zaher
Khan, Rawaiz
Zaini, Sakawi
Muhammad, Aqif
Haider, Adnan
Sumaiya, Zainal Abidin
author_sort Nawaz, Rab
building UMP Institutional Repository
collection Online Access
description Herein, black titania nanoparticles (BTNs) were synthesized via chloride sol–gel route which were then employed for the remediation of phenolic compounds (PCs) contaminated wastewater. A total of 2.70 L of input reagents and 28.33 kWh of electrical energy (EE) were required to produce 1 kilogramme of BTNs at a cost of 1231.872 dollars. The performance of BTNs for the degradation of PCs was significantly affected by various reaction conditions, which were optimized at 1.2 g/L of BTNs, 0.04 mol/L of H2O2, 30 mg/L of PCs concentration, and pH of 7.4 using statistical and machine learning (ML) models. Operated under optimal conditions and visible light, the photocatalytic system based on BTNs augmented by H2O2 consumed 1261.17 kWh/m3 of EE for removing more than 90 % of PCs and COD at a treatment cost (t-cost) of 66.84 $/m3 .
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institution Universiti Malaysia Pahang
institution_category Local University
language English
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publishDate 2025
publisher Elsevier
recordtype eprints
repository_type Digital Repository
spelling ump-444162025-04-29T06:37:23Z http://umpir.ump.edu.my/id/eprint/44416/ Visible-driven industrial wastewater remediation using black titania: optimization, energy consumption, treatment, and material preparation costs estimation Nawaz, Rab Arshad, Ushtar Marlia, Mohd Hanafiah Haider, Sajjad Anjum, Muzammil Abdel Baki, Zaher Khan, Rawaiz Zaini, Sakawi Muhammad, Aqif Haider, Adnan Sumaiya, Zainal Abidin TA Engineering (General). Civil engineering (General) TD Environmental technology. Sanitary engineering TP Chemical technology Herein, black titania nanoparticles (BTNs) were synthesized via chloride sol–gel route which were then employed for the remediation of phenolic compounds (PCs) contaminated wastewater. A total of 2.70 L of input reagents and 28.33 kWh of electrical energy (EE) were required to produce 1 kilogramme of BTNs at a cost of 1231.872 dollars. The performance of BTNs for the degradation of PCs was significantly affected by various reaction conditions, which were optimized at 1.2 g/L of BTNs, 0.04 mol/L of H2O2, 30 mg/L of PCs concentration, and pH of 7.4 using statistical and machine learning (ML) models. Operated under optimal conditions and visible light, the photocatalytic system based on BTNs augmented by H2O2 consumed 1261.17 kWh/m3 of EE for removing more than 90 % of PCs and COD at a treatment cost (t-cost) of 66.84 $/m3 . Elsevier 2025-03 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/44416/1/Visible-driven%20industrial%20wastewater%20remediation%20using%20black%20titania.pdf Nawaz, Rab and Arshad, Ushtar and Marlia, Mohd Hanafiah and Haider, Sajjad and Anjum, Muzammil and Abdel Baki, Zaher and Khan, Rawaiz and Zaini, Sakawi and Muhammad, Aqif and Haider, Adnan and Sumaiya, Zainal Abidin (2025) Visible-driven industrial wastewater remediation using black titania: optimization, energy consumption, treatment, and material preparation costs estimation. Chemical Engineering Science, 306 (121257). pp. 1-20. ISSN 0009-2509. (Published) https://doi.org/10.1016/j.ces.2025.121257 https://doi.org/10.1016/j.ces.2025.121257
spellingShingle TA Engineering (General). Civil engineering (General)
TD Environmental technology. Sanitary engineering
TP Chemical technology
Nawaz, Rab
Arshad, Ushtar
Marlia, Mohd Hanafiah
Haider, Sajjad
Anjum, Muzammil
Abdel Baki, Zaher
Khan, Rawaiz
Zaini, Sakawi
Muhammad, Aqif
Haider, Adnan
Sumaiya, Zainal Abidin
Visible-driven industrial wastewater remediation using black titania: optimization, energy consumption, treatment, and material preparation costs estimation
title Visible-driven industrial wastewater remediation using black titania: optimization, energy consumption, treatment, and material preparation costs estimation
title_full Visible-driven industrial wastewater remediation using black titania: optimization, energy consumption, treatment, and material preparation costs estimation
title_fullStr Visible-driven industrial wastewater remediation using black titania: optimization, energy consumption, treatment, and material preparation costs estimation
title_full_unstemmed Visible-driven industrial wastewater remediation using black titania: optimization, energy consumption, treatment, and material preparation costs estimation
title_short Visible-driven industrial wastewater remediation using black titania: optimization, energy consumption, treatment, and material preparation costs estimation
title_sort visible-driven industrial wastewater remediation using black titania: optimization, energy consumption, treatment, and material preparation costs estimation
topic TA Engineering (General). Civil engineering (General)
TD Environmental technology. Sanitary engineering
TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/44416/
http://umpir.ump.edu.my/id/eprint/44416/
http://umpir.ump.edu.my/id/eprint/44416/
http://umpir.ump.edu.my/id/eprint/44416/1/Visible-driven%20industrial%20wastewater%20remediation%20using%20black%20titania.pdf