Investigation of heavy metal concentrations for biocoke by using ICP-OES

The palm oil industry produces large amounts of empty oil palm bunches (EFB) waste, which can pollute the environment if it contains hazardous heavy metals. This study aims to analyze the concentration of heavy metals in EFB using the Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES...

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Main Authors: Erdiwansyah, E., Gani, Asri, Desvita, Hera, Mahidin, M., Bahagia, Bahagia, Rizalman, Mamat, Mohd Rosdi, Salleh
Format: Article
Language:English
Published: Elsevier B.V. 2025
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/43807/
http://umpir.ump.edu.my/id/eprint/43807/1/Investigation%20of%20heavy%20metal%20concentrations%20for%20biocoke%20by%20using%20ICP-OES.pdf
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author Erdiwansyah, E.
Gani, Asri
Desvita, Hera
Mahidin, M.
Bahagia, Bahagia
Rizalman, Mamat
Mohd Rosdi, Salleh
author_facet Erdiwansyah, E.
Gani, Asri
Desvita, Hera
Mahidin, M.
Bahagia, Bahagia
Rizalman, Mamat
Mohd Rosdi, Salleh
author_sort Erdiwansyah, E.
building UMP Institutional Repository
collection Online Access
description The palm oil industry produces large amounts of empty oil palm bunches (EFB) waste, which can pollute the environment if it contains hazardous heavy metals. This study aims to analyze the concentration of heavy metals in EFB using the Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) method. The analysis showed that hazardous heavy metals such as arsenic (As), cadmium (Cd), mercury (Hg), and lithium (Li) were not detected in EFB samples. Calcium (Ca) was recorded as the metal with the highest concentration of 52.636,42 µg/g, followed by sodium (Na) at 863,67 µg/g and copper (Cu) at 6.12 µg/g. Variations in soaking temperature and water flow rate in the EFB preparation process affected the concentration of certain metals, such as a significant increase in Ca with increasing flow rate. These results indicate that EFB is relatively safe to use as a raw material for biocoke. It can partially replace coal as an alternative fuel in the combustion process because its calorific value is close to coal. In addition to supporting emission reduction efforts, this study provides a scientific basis for a more environmentally friendly and sustainable palm oil industry waste management strategy and opportunities for developing alternative fuels from biomass that can help improve energy efficiency in various industrial applications.
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spelling ump-438072025-02-13T08:38:31Z http://umpir.ump.edu.my/id/eprint/43807/ Investigation of heavy metal concentrations for biocoke by using ICP-OES Erdiwansyah, E. Gani, Asri Desvita, Hera Mahidin, M. Bahagia, Bahagia Rizalman, Mamat Mohd Rosdi, Salleh T Technology (General) TA Engineering (General). Civil engineering (General) TJ Mechanical engineering and machinery TL Motor vehicles. Aeronautics. Astronautics The palm oil industry produces large amounts of empty oil palm bunches (EFB) waste, which can pollute the environment if it contains hazardous heavy metals. This study aims to analyze the concentration of heavy metals in EFB using the Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) method. The analysis showed that hazardous heavy metals such as arsenic (As), cadmium (Cd), mercury (Hg), and lithium (Li) were not detected in EFB samples. Calcium (Ca) was recorded as the metal with the highest concentration of 52.636,42 µg/g, followed by sodium (Na) at 863,67 µg/g and copper (Cu) at 6.12 µg/g. Variations in soaking temperature and water flow rate in the EFB preparation process affected the concentration of certain metals, such as a significant increase in Ca with increasing flow rate. These results indicate that EFB is relatively safe to use as a raw material for biocoke. It can partially replace coal as an alternative fuel in the combustion process because its calorific value is close to coal. In addition to supporting emission reduction efforts, this study provides a scientific basis for a more environmentally friendly and sustainable palm oil industry waste management strategy and opportunities for developing alternative fuels from biomass that can help improve energy efficiency in various industrial applications. Elsevier B.V. 2025 Article PeerReviewed pdf en cc_by_nc_4 http://umpir.ump.edu.my/id/eprint/43807/1/Investigation%20of%20heavy%20metal%20concentrations%20for%20biocoke%20by%20using%20ICP-OES.pdf Erdiwansyah, E. and Gani, Asri and Desvita, Hera and Mahidin, M. and Bahagia, Bahagia and Rizalman, Mamat and Mohd Rosdi, Salleh (2025) Investigation of heavy metal concentrations for biocoke by using ICP-OES. Results in Engineering, 25 (103717). pp. 1-10. ISSN 2590-1230. (Published) https://doi.org/10.1016/j.rineng.2024.103717 https://doi.org/10.1016/j.rineng.2024.103717
spellingShingle T Technology (General)
TA Engineering (General). Civil engineering (General)
TJ Mechanical engineering and machinery
TL Motor vehicles. Aeronautics. Astronautics
Erdiwansyah, E.
Gani, Asri
Desvita, Hera
Mahidin, M.
Bahagia, Bahagia
Rizalman, Mamat
Mohd Rosdi, Salleh
Investigation of heavy metal concentrations for biocoke by using ICP-OES
title Investigation of heavy metal concentrations for biocoke by using ICP-OES
title_full Investigation of heavy metal concentrations for biocoke by using ICP-OES
title_fullStr Investigation of heavy metal concentrations for biocoke by using ICP-OES
title_full_unstemmed Investigation of heavy metal concentrations for biocoke by using ICP-OES
title_short Investigation of heavy metal concentrations for biocoke by using ICP-OES
title_sort investigation of heavy metal concentrations for biocoke by using icp-oes
topic T Technology (General)
TA Engineering (General). Civil engineering (General)
TJ Mechanical engineering and machinery
TL Motor vehicles. Aeronautics. Astronautics
url http://umpir.ump.edu.my/id/eprint/43807/
http://umpir.ump.edu.my/id/eprint/43807/
http://umpir.ump.edu.my/id/eprint/43807/
http://umpir.ump.edu.my/id/eprint/43807/1/Investigation%20of%20heavy%20metal%20concentrations%20for%20biocoke%20by%20using%20ICP-OES.pdf