CO2 reforming of CH4 on mesoporous alumina‑supported cobalt catalyst: optimization of lanthana promoter loading
The impact of La2O3 promoter loading on alumina-supported cobalt catalysts was investigated in terms of physicochemical properties and catalytic performance for CO2 reforming of methane (CRM) at stoichiometric CH4/CO2 ratio and 1023 K. Both Co3O4 (with crystal size: 5.2–8.4 nm) and La2O3 nanoparticl...
| Main Authors: | , , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
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Springer Nature
2021
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| Online Access: | http://umpir.ump.edu.my/id/eprint/31624/ http://umpir.ump.edu.my/id/eprint/31624/1/Paper%203.pdf |
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| author | Tran, Ngoc Thang P. Senthil, Kumar Le, Quyet Van Cuong, Nguyen Van Phuong, Pham T. T. A. A., Jalil Sharma, Gaurav Kumar, Amit Sharma, Ajit Ayodele, Bamidele Victor Sumaiya, Zainal Abidin Vo, Dai‑Viet N |
| author_facet | Tran, Ngoc Thang P. Senthil, Kumar Le, Quyet Van Cuong, Nguyen Van Phuong, Pham T. T. A. A., Jalil Sharma, Gaurav Kumar, Amit Sharma, Ajit Ayodele, Bamidele Victor Sumaiya, Zainal Abidin Vo, Dai‑Viet N |
| author_sort | Tran, Ngoc Thang |
| building | UMP Institutional Repository |
| collection | Online Access |
| description | The impact of La2O3 promoter loading on alumina-supported cobalt catalysts was investigated in terms of physicochemical properties and catalytic performance for CO2 reforming of methane (CRM) at stoichiometric CH4/CO2 ratio and 1023 K. Both Co3O4 (with crystal size: 5.2–8.4 nm) and La2O3 nanoparticles were finely dispersed on support surface. The promotional La2O3 effect could noticeably increase CH4 and CO2 conversions to 29.3% and 17.3%, correspondingly due to improved basic site concentration and decreasing crystallite size of active metal in association with promoter addition. 5%La loading was an optimal promoter content for reactant conversions as well as yield of H2 and CO. 5%La-10%Co/Al2O3 also exhibited the highest resistance to carbon deposition owing to the basic nature, redox feature and oxygen vacancy of La2O3 dopant. Notably, the H2/CO ratio obtained within 0.84–0.98 is preferable for Fischer-Tropsch reaction in downstream to yield liquid hydrocarbon fuels. |
| first_indexed | 2025-11-15T03:03:07Z |
| format | Article |
| id | ump-31624 |
| institution | Universiti Malaysia Pahang |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T03:03:07Z |
| publishDate | 2021 |
| publisher | Springer Nature |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | ump-316242021-07-15T07:54:50Z http://umpir.ump.edu.my/id/eprint/31624/ CO2 reforming of CH4 on mesoporous alumina‑supported cobalt catalyst: optimization of lanthana promoter loading Tran, Ngoc Thang P. Senthil, Kumar Le, Quyet Van Cuong, Nguyen Van Phuong, Pham T. T. A. A., Jalil Sharma, Gaurav Kumar, Amit Sharma, Ajit Ayodele, Bamidele Victor Sumaiya, Zainal Abidin Vo, Dai‑Viet N T Technology (General) TA Engineering (General). Civil engineering (General) TJ Mechanical engineering and machinery TP Chemical technology The impact of La2O3 promoter loading on alumina-supported cobalt catalysts was investigated in terms of physicochemical properties and catalytic performance for CO2 reforming of methane (CRM) at stoichiometric CH4/CO2 ratio and 1023 K. Both Co3O4 (with crystal size: 5.2–8.4 nm) and La2O3 nanoparticles were finely dispersed on support surface. The promotional La2O3 effect could noticeably increase CH4 and CO2 conversions to 29.3% and 17.3%, correspondingly due to improved basic site concentration and decreasing crystallite size of active metal in association with promoter addition. 5%La loading was an optimal promoter content for reactant conversions as well as yield of H2 and CO. 5%La-10%Co/Al2O3 also exhibited the highest resistance to carbon deposition owing to the basic nature, redox feature and oxygen vacancy of La2O3 dopant. Notably, the H2/CO ratio obtained within 0.84–0.98 is preferable for Fischer-Tropsch reaction in downstream to yield liquid hydrocarbon fuels. Springer Nature 2021-03-12 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/31624/1/Paper%203.pdf Tran, Ngoc Thang and P. Senthil, Kumar and Le, Quyet Van and Cuong, Nguyen Van and Phuong, Pham T. T. and A. A., Jalil and Sharma, Gaurav and Kumar, Amit and Sharma, Ajit and Ayodele, Bamidele Victor and Sumaiya, Zainal Abidin and Vo, Dai‑Viet N (2021) CO2 reforming of CH4 on mesoporous alumina‑supported cobalt catalyst: optimization of lanthana promoter loading. Topics in Catalysis. pp. 1-11. (Published) https://doi.org/10.1007/s11244-021-01428-x |
| spellingShingle | T Technology (General) TA Engineering (General). Civil engineering (General) TJ Mechanical engineering and machinery TP Chemical technology Tran, Ngoc Thang P. Senthil, Kumar Le, Quyet Van Cuong, Nguyen Van Phuong, Pham T. T. A. A., Jalil Sharma, Gaurav Kumar, Amit Sharma, Ajit Ayodele, Bamidele Victor Sumaiya, Zainal Abidin Vo, Dai‑Viet N CO2 reforming of CH4 on mesoporous alumina‑supported cobalt catalyst: optimization of lanthana promoter loading |
| title | CO2 reforming of CH4 on mesoporous alumina‑supported cobalt catalyst: optimization of lanthana promoter loading |
| title_full | CO2 reforming of CH4 on mesoporous alumina‑supported cobalt catalyst: optimization of lanthana promoter loading |
| title_fullStr | CO2 reforming of CH4 on mesoporous alumina‑supported cobalt catalyst: optimization of lanthana promoter loading |
| title_full_unstemmed | CO2 reforming of CH4 on mesoporous alumina‑supported cobalt catalyst: optimization of lanthana promoter loading |
| title_short | CO2 reforming of CH4 on mesoporous alumina‑supported cobalt catalyst: optimization of lanthana promoter loading |
| title_sort | co2 reforming of ch4 on mesoporous alumina‑supported cobalt catalyst: optimization of lanthana promoter loading |
| topic | T Technology (General) TA Engineering (General). Civil engineering (General) TJ Mechanical engineering and machinery TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/31624/ http://umpir.ump.edu.my/id/eprint/31624/ http://umpir.ump.edu.my/id/eprint/31624/1/Paper%203.pdf |