Preliminary investigations in the synthesis of epoxidized natural rubber based conducting polymer / Chan Chin Han

The electrical conductivity and glass transition temperature of epoxidized natural rubber / polyethylene oxide) (ENR/PEO) blends and ENR/PEO blends doped with lithium perchlorate (UCIO4) have been investigated by using solution casting method. Conductivities {a) of the solid polymer electrolyte film...

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Main Author: Chan, Chin Han
Format: Research Reports
Language:English
Published: Institute of Research, Development and Commercialization, Universiti Teknologi MARA 2006
Subjects:
Online Access:https://ir.uitm.edu.my/id/eprint/7826/
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author Chan, Chin Han
author_facet Chan, Chin Han
author_sort Chan, Chin Han
building UiTM Institutional Repository
collection Online Access
description The electrical conductivity and glass transition temperature of epoxidized natural rubber / polyethylene oxide) (ENR/PEO) blends and ENR/PEO blends doped with lithium perchlorate (UCIO4) have been investigated by using solution casting method. Conductivities {a) of the solid polymer electrolyte films were measured by impedance spectrometer and glass transition temperatures (rgs) were measured by differential scanning calorimetry. ENR/PEO 40/60 shows the highest ionic conductivities at (4.02± 0.02) x 10"8 S/cm. Afterwards, ENR/PEO 40/60 was doped with various wt % of LiC104. 12 wt % of UCIO4 relative to the dry weight of polymer film shows the highest conductivity for ENR/PEO 40/60 blends at (1600 ± 100) x 10"8 S/cm. The T% for pure PEO is found at -54 °C, and the Ts for pure ENR is found at -19 °C. The addition of LiC104 salts in ENR/PEO blends causes the increases of T% for PEO and ENR.
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spelling uitm-78262023-11-08T02:26:23Z https://ir.uitm.edu.my/id/eprint/7826/ Preliminary investigations in the synthesis of epoxidized natural rubber based conducting polymer / Chan Chin Han Chan, Chin Han QD Chemistry Polymers and polymer manufacture The electrical conductivity and glass transition temperature of epoxidized natural rubber / polyethylene oxide) (ENR/PEO) blends and ENR/PEO blends doped with lithium perchlorate (UCIO4) have been investigated by using solution casting method. Conductivities {a) of the solid polymer electrolyte films were measured by impedance spectrometer and glass transition temperatures (rgs) were measured by differential scanning calorimetry. ENR/PEO 40/60 shows the highest ionic conductivities at (4.02± 0.02) x 10"8 S/cm. Afterwards, ENR/PEO 40/60 was doped with various wt % of LiC104. 12 wt % of UCIO4 relative to the dry weight of polymer film shows the highest conductivity for ENR/PEO 40/60 blends at (1600 ± 100) x 10"8 S/cm. The T% for pure PEO is found at -54 °C, and the Ts for pure ENR is found at -19 °C. The addition of LiC104 salts in ENR/PEO blends causes the increases of T% for PEO and ENR. Institute of Research, Development and Commercialization, Universiti Teknologi MARA 2006 Research Reports NonPeerReviewed text en https://ir.uitm.edu.my/id/eprint/7826/2/7826.pdf Chan, Chin Han (2006) Preliminary investigations in the synthesis of epoxidized natural rubber based conducting polymer / Chan Chin Han. (2006) [Research Reports] <http://terminalib.uitm.edu.my/7826.pdf> (Unpublished)
spellingShingle QD Chemistry
Polymers and polymer manufacture
Chan, Chin Han
Preliminary investigations in the synthesis of epoxidized natural rubber based conducting polymer / Chan Chin Han
title Preliminary investigations in the synthesis of epoxidized natural rubber based conducting polymer / Chan Chin Han
title_full Preliminary investigations in the synthesis of epoxidized natural rubber based conducting polymer / Chan Chin Han
title_fullStr Preliminary investigations in the synthesis of epoxidized natural rubber based conducting polymer / Chan Chin Han
title_full_unstemmed Preliminary investigations in the synthesis of epoxidized natural rubber based conducting polymer / Chan Chin Han
title_short Preliminary investigations in the synthesis of epoxidized natural rubber based conducting polymer / Chan Chin Han
title_sort preliminary investigations in the synthesis of epoxidized natural rubber based conducting polymer / chan chin han
topic QD Chemistry
Polymers and polymer manufacture
url https://ir.uitm.edu.my/id/eprint/7826/