Synthesis and characterization of Palladium(Ii) and Nickel(Ii) complexes of schiff bases and the potential of the Palladium (Ii) complexes as catalysts for C-C bond formation / Amalina Mohd Tajuddin

This study reports the synthesis, characterization and catalytic activities of palladium(II) Schiff base complexes, both as homogeneous and MCM-41 supported heterogeneous catalysts for cross-coupling C-C bond formation reactions. Three broad groups of inexpensive Schiff base ligands (L1, L2 and L3)...

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Main Author: Mohd Tajuddin, Amalina
Format: Book Section
Language:English
Published: Institute of Graduate Studies, UiTM 2014
Subjects:
Online Access:https://ir.uitm.edu.my/id/eprint/19554/
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author Mohd Tajuddin, Amalina
author_facet Mohd Tajuddin, Amalina
author_sort Mohd Tajuddin, Amalina
building UiTM Institutional Repository
collection Online Access
description This study reports the synthesis, characterization and catalytic activities of palladium(II) Schiff base complexes, both as homogeneous and MCM-41 supported heterogeneous catalysts for cross-coupling C-C bond formation reactions. Three broad groups of inexpensive Schiff base ligands (L1, L2 and L3) have been synthesized through condensation process between four benzylamine derivatives with aldehyde or ketone in 1:1 molar ratio. 12 ligands and 20 metal complexes of Pd(II) and Ni(II) have been successfully obtained. The metal complexes were prepared through the complexation reaction between the Schiff base ligands with Pd(II) and Ni(II) acetates in a 2:1 molar ratio.
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spelling uitm-195542018-06-12T02:24:56Z https://ir.uitm.edu.my/id/eprint/19554/ Synthesis and characterization of Palladium(Ii) and Nickel(Ii) complexes of schiff bases and the potential of the Palladium (Ii) complexes as catalysts for C-C bond formation / Amalina Mohd Tajuddin Mohd Tajuddin, Amalina Malaysia This study reports the synthesis, characterization and catalytic activities of palladium(II) Schiff base complexes, both as homogeneous and MCM-41 supported heterogeneous catalysts for cross-coupling C-C bond formation reactions. Three broad groups of inexpensive Schiff base ligands (L1, L2 and L3) have been synthesized through condensation process between four benzylamine derivatives with aldehyde or ketone in 1:1 molar ratio. 12 ligands and 20 metal complexes of Pd(II) and Ni(II) have been successfully obtained. The metal complexes were prepared through the complexation reaction between the Schiff base ligands with Pd(II) and Ni(II) acetates in a 2:1 molar ratio. Institute of Graduate Studies, UiTM 2014 Book Section PeerReviewed text en https://ir.uitm.edu.my/id/eprint/19554/1/ABS_AMALINA%20MOHD%20TAJUDDIN%20TDRA%20VOL%206%20IGS_14.pdf Mohd Tajuddin, Amalina (2014) Synthesis and characterization of Palladium(Ii) and Nickel(Ii) complexes of schiff bases and the potential of the Palladium (Ii) complexes as catalysts for C-C bond formation / Amalina Mohd Tajuddin. (2014) In: The Doctoral Research Abstracts. IPSis Biannual Publication, 6 (6). Institute of Graduate Studies, UiTM, Shah Alam.
spellingShingle Malaysia
Mohd Tajuddin, Amalina
Synthesis and characterization of Palladium(Ii) and Nickel(Ii) complexes of schiff bases and the potential of the Palladium (Ii) complexes as catalysts for C-C bond formation / Amalina Mohd Tajuddin
title Synthesis and characterization of Palladium(Ii) and Nickel(Ii) complexes of schiff bases and the potential of the Palladium (Ii) complexes as catalysts for C-C bond formation / Amalina Mohd Tajuddin
title_full Synthesis and characterization of Palladium(Ii) and Nickel(Ii) complexes of schiff bases and the potential of the Palladium (Ii) complexes as catalysts for C-C bond formation / Amalina Mohd Tajuddin
title_fullStr Synthesis and characterization of Palladium(Ii) and Nickel(Ii) complexes of schiff bases and the potential of the Palladium (Ii) complexes as catalysts for C-C bond formation / Amalina Mohd Tajuddin
title_full_unstemmed Synthesis and characterization of Palladium(Ii) and Nickel(Ii) complexes of schiff bases and the potential of the Palladium (Ii) complexes as catalysts for C-C bond formation / Amalina Mohd Tajuddin
title_short Synthesis and characterization of Palladium(Ii) and Nickel(Ii) complexes of schiff bases and the potential of the Palladium (Ii) complexes as catalysts for C-C bond formation / Amalina Mohd Tajuddin
title_sort synthesis and characterization of palladium(ii) and nickel(ii) complexes of schiff bases and the potential of the palladium (ii) complexes as catalysts for c-c bond formation / amalina mohd tajuddin
topic Malaysia
url https://ir.uitm.edu.my/id/eprint/19554/