Nickel Slag/Laterite Soil and Nickel Slag/Iron Sand Nanocomposites: Structural, Optical, and Electromagnetic Absorption Properties

Efforts to produce microwave absorber materials that are inexpensive and environmentally friendly have become a means of greening the environment. The breakthrough can be focused on industrial waste and natural materials for functional purposes and how to enhance their performance. We successfully s...

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Main Authors: Heryanto, Heryanto, Siswanto, Siswanto, Rahmat, Roni, Sulieman, Abdelmoneim, Bradley, D.A. *, Tahir, Dahlang
Format: Article
Language:English
Published: American Chemical Society 2023
Subjects:
Online Access:http://eprints.sunway.edu.my/2278/
http://eprints.sunway.edu.my/2278/1/67.pdf
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author Heryanto, Heryanto
Siswanto, Siswanto
Rahmat, Roni
Sulieman, Abdelmoneim
Bradley, D.A. *
Tahir, Dahlang
author_facet Heryanto, Heryanto
Siswanto, Siswanto
Rahmat, Roni
Sulieman, Abdelmoneim
Bradley, D.A. *
Tahir, Dahlang
author_sort Heryanto, Heryanto
building SU Institutional Repository
collection Online Access
description Efforts to produce microwave absorber materials that are inexpensive and environmentally friendly have become a means of greening the environment. The breakthrough can be focused on industrial waste and natural materials for functional purposes and how to enhance their performance. We successfully synthesized nickel slag/laterite soil (NS/LS) and nickel slag/iron sand (NS/IS) nanocomposites using a simple mechanical alloying technique, and the electromagnetic (EM) wave absorption capacities of the nanocomposites were measured using a vector network analyzer. The structural properties of the nanocomposites were analyzed by X-ray diffraction spectroscopy, where the results of the analysis showed that NS/IS has the largest crystallite size (15.69 nm) and the highest EM wave absorption performance. The optical properties of the nanocomposites were determined from their Fourier transform infrared spectra using the Kramers–Kronig relation. As determined through a quantitative analysis of the optical properties, the distance between the longitudinal and transversal optical phonon wavenumber positions (Δ(LO – TO) = 65 cm–1) is inversely proportional to the reflection loss. The surface morphologies of the nanocomposites were analyzed by scanning electron microscopy, and the particle diameters were observed by binary image and Gaussian distribution analyses. The nanocomposite surface exhibits a graded-like morphology, which indicates multiple reflections of the EM radiation, consequently reducing the EM interference. The best nanocomposite for an attenuated EM wave achieved a reflection loss of −39.14 dB at 5–8 GHz. A low penetration depth has implications for the electrical charge tuning of the storage and composite magnets. Finally, the EM absorption properties of NS/IS and NS/LS indicate a 2-mm-thick environmentally friendly nanocomposite for EM absorption.
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spelling sunway-22782023-06-17T12:36:38Z http://eprints.sunway.edu.my/2278/ Nickel Slag/Laterite Soil and Nickel Slag/Iron Sand Nanocomposites: Structural, Optical, and Electromagnetic Absorption Properties Heryanto, Heryanto Siswanto, Siswanto Rahmat, Roni Sulieman, Abdelmoneim Bradley, D.A. * Tahir, Dahlang QC Physics TA Engineering (General). Civil engineering (General) Efforts to produce microwave absorber materials that are inexpensive and environmentally friendly have become a means of greening the environment. The breakthrough can be focused on industrial waste and natural materials for functional purposes and how to enhance their performance. We successfully synthesized nickel slag/laterite soil (NS/LS) and nickel slag/iron sand (NS/IS) nanocomposites using a simple mechanical alloying technique, and the electromagnetic (EM) wave absorption capacities of the nanocomposites were measured using a vector network analyzer. The structural properties of the nanocomposites were analyzed by X-ray diffraction spectroscopy, where the results of the analysis showed that NS/IS has the largest crystallite size (15.69 nm) and the highest EM wave absorption performance. The optical properties of the nanocomposites were determined from their Fourier transform infrared spectra using the Kramers–Kronig relation. As determined through a quantitative analysis of the optical properties, the distance between the longitudinal and transversal optical phonon wavenumber positions (Δ(LO – TO) = 65 cm–1) is inversely proportional to the reflection loss. The surface morphologies of the nanocomposites were analyzed by scanning electron microscopy, and the particle diameters were observed by binary image and Gaussian distribution analyses. The nanocomposite surface exhibits a graded-like morphology, which indicates multiple reflections of the EM radiation, consequently reducing the EM interference. The best nanocomposite for an attenuated EM wave achieved a reflection loss of −39.14 dB at 5–8 GHz. A low penetration depth has implications for the electrical charge tuning of the storage and composite magnets. Finally, the EM absorption properties of NS/IS and NS/LS indicate a 2-mm-thick environmentally friendly nanocomposite for EM absorption. American Chemical Society 2023-05-18 Article PeerReviewed text en cc_by_nc_nd_4 http://eprints.sunway.edu.my/2278/1/67.pdf Heryanto, Heryanto and Siswanto, Siswanto and Rahmat, Roni and Sulieman, Abdelmoneim and Bradley, D.A. * and Tahir, Dahlang (2023) Nickel Slag/Laterite Soil and Nickel Slag/Iron Sand Nanocomposites: Structural, Optical, and Electromagnetic Absorption Properties. ACS Omega, 8 (21). pp. 18591-18602. ISSN 2470-1343 https://doi.org/10.1021/acsomega.3c00423 10.1021/acsomega.3c00423
spellingShingle QC Physics
TA Engineering (General). Civil engineering (General)
Heryanto, Heryanto
Siswanto, Siswanto
Rahmat, Roni
Sulieman, Abdelmoneim
Bradley, D.A. *
Tahir, Dahlang
Nickel Slag/Laterite Soil and Nickel Slag/Iron Sand Nanocomposites: Structural, Optical, and Electromagnetic Absorption Properties
title Nickel Slag/Laterite Soil and Nickel Slag/Iron Sand Nanocomposites: Structural, Optical, and Electromagnetic Absorption Properties
title_full Nickel Slag/Laterite Soil and Nickel Slag/Iron Sand Nanocomposites: Structural, Optical, and Electromagnetic Absorption Properties
title_fullStr Nickel Slag/Laterite Soil and Nickel Slag/Iron Sand Nanocomposites: Structural, Optical, and Electromagnetic Absorption Properties
title_full_unstemmed Nickel Slag/Laterite Soil and Nickel Slag/Iron Sand Nanocomposites: Structural, Optical, and Electromagnetic Absorption Properties
title_short Nickel Slag/Laterite Soil and Nickel Slag/Iron Sand Nanocomposites: Structural, Optical, and Electromagnetic Absorption Properties
title_sort nickel slag/laterite soil and nickel slag/iron sand nanocomposites: structural, optical, and electromagnetic absorption properties
topic QC Physics
TA Engineering (General). Civil engineering (General)
url http://eprints.sunway.edu.my/2278/
http://eprints.sunway.edu.my/2278/
http://eprints.sunway.edu.my/2278/
http://eprints.sunway.edu.my/2278/1/67.pdf