Suppression of inhibition of substrate photodegradation by scavengers of hydroxyl radicals: the solvent-cage effect of bromide on nitrate photolysis

Suppression of inhibition of substrate photodegradation by scavengers of hydroxyl radicals: the solvent-cage effect of bromide on nitrate photolysis

In this paper we show that bromide scavenges the (OH)-O-center dot radicals formed upon photolysis of nitrate, before they leave the solvent cage. Bromide can thus inhibit the in-cage recombination between (OH)-O-center dot and (NO2)-N-center dot. The consequence is an increased generation of (NO2)...

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Bibliographic Details
Main Authors: Radharani, Das, Binay K., Dutta, Valter, Maurino, Davide, Vione, Claudio, Minero
Format: Article
Language:English
Published: SPRINGER HEIDELBERG, TIERGARTENSTRASSE 17, D-69121 HEIDELBERG, GERMANY 2009
Subjects:
TD Environmental technology. Sanitary engineering
Online Access:http://scholars.utp.edu.my/id/eprint/2341/
http://scholars.utp.edu.my/id/eprint/2341/1/SAMPLE_PAPER_PDF.pdf

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