Suppression of inhibition of substrate photodegradation by scavengers of hydroxyl radicals: the solvent-cage effect of bromide on nitrate photolysis
In this paper we show that bromide scavenges the (OH)-O-center dot radicals formed upon photolysis of nitrate, before they leave the solvent cage. Bromide can thus inhibit the in-cage recombination between (OH)-O-center dot and (NO2)-N-center dot. The consequence is an increased generation of (NO2)...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
SPRINGER HEIDELBERG, TIERGARTENSTRASSE 17, D-69121 HEIDELBERG, GERMANY
2009
|
| Subjects: | |
| Online Access: | http://scholars.utp.edu.my/id/eprint/2341/ http://scholars.utp.edu.my/id/eprint/2341/1/SAMPLE_PAPER_PDF.pdf |