Can bioluminescence resonance energy transfer be used to elucidate structural and binding information about the ABCG2 transporter?

ATP binding cassette G2 (ABCG2) is a multidrug transporter involved in cancer cell resistance to chemotherapeutics. Uncovering ABCG2 structural and binding information and screening for potential inhibitors is crucial for increasing chemotherapy effectiveness and improving cancer prognoses. The pres...

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Main Author: Morris, Joseph
Format: Thesis (University of Nottingham only)
Language:English
Published: 2022
Subjects:
Online Access:https://eprints.nottingham.ac.uk/68414/
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author Morris, Joseph
author_facet Morris, Joseph
author_sort Morris, Joseph
building Nottingham Research Data Repository
collection Online Access
description ATP binding cassette G2 (ABCG2) is a multidrug transporter involved in cancer cell resistance to chemotherapeutics. Uncovering ABCG2 structural and binding information and screening for potential inhibitors is crucial for increasing chemotherapy effectiveness and improving cancer prognoses. The present study examines the potential for bioluminescence resonance energy transfer (BRET) to report on ABCG2: substrate interactions, transporter conformation, and substrate specificity. Three NanoLuc-tagged mutant ABCG2 isoforms designed to alter substrate affinity and specificity were generated and expressed in HEK293T cells and membrane suspensions. NanoBRET assays were carried out in cells and membranes with a concentration range of fluorescent substrates mitoxantrone and rhodamine 123, sometimes in the presence of ABCG2 inhibitor Ko143 and a range of additives. NanoBRET successfully reported on binding of rhodamine 123 by ABCG2 through positive dose-response, however nonspecific BRET effects and/or low affinity substrates prevented the transporter from saturating. This bystander BRET effect appeared to mask differences between ABCG2 constructs, and the effect of Ko143. Therefore, further research with higher affinity ligands or substrates alongside more comparable control cell lines in parallel is required to fully evaluate BRET with ABCG2.
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spelling nottingham-684142022-07-31T04:41:17Z https://eprints.nottingham.ac.uk/68414/ Can bioluminescence resonance energy transfer be used to elucidate structural and binding information about the ABCG2 transporter? Morris, Joseph ATP binding cassette G2 (ABCG2) is a multidrug transporter involved in cancer cell resistance to chemotherapeutics. Uncovering ABCG2 structural and binding information and screening for potential inhibitors is crucial for increasing chemotherapy effectiveness and improving cancer prognoses. The present study examines the potential for bioluminescence resonance energy transfer (BRET) to report on ABCG2: substrate interactions, transporter conformation, and substrate specificity. Three NanoLuc-tagged mutant ABCG2 isoforms designed to alter substrate affinity and specificity were generated and expressed in HEK293T cells and membrane suspensions. NanoBRET assays were carried out in cells and membranes with a concentration range of fluorescent substrates mitoxantrone and rhodamine 123, sometimes in the presence of ABCG2 inhibitor Ko143 and a range of additives. NanoBRET successfully reported on binding of rhodamine 123 by ABCG2 through positive dose-response, however nonspecific BRET effects and/or low affinity substrates prevented the transporter from saturating. This bystander BRET effect appeared to mask differences between ABCG2 constructs, and the effect of Ko143. Therefore, further research with higher affinity ligands or substrates alongside more comparable control cell lines in parallel is required to fully evaluate BRET with ABCG2. 2022-07-31 Thesis (University of Nottingham only) NonPeerReviewed application/pdf en cc_by https://eprints.nottingham.ac.uk/68414/1/Joe%20Morris%20Final%20Updated%20Thesis.pdf Morris, Joseph (2022) Can bioluminescence resonance energy transfer be used to elucidate structural and binding information about the ABCG2 transporter? MRes thesis, University of Nottingham. ATP binding cassette G2 ABCG2 Bioluminescence resonance energy transfer BRET
spellingShingle ATP binding cassette G2
ABCG2
Bioluminescence resonance energy transfer
BRET
Morris, Joseph
Can bioluminescence resonance energy transfer be used to elucidate structural and binding information about the ABCG2 transporter?
title Can bioluminescence resonance energy transfer be used to elucidate structural and binding information about the ABCG2 transporter?
title_full Can bioluminescence resonance energy transfer be used to elucidate structural and binding information about the ABCG2 transporter?
title_fullStr Can bioluminescence resonance energy transfer be used to elucidate structural and binding information about the ABCG2 transporter?
title_full_unstemmed Can bioluminescence resonance energy transfer be used to elucidate structural and binding information about the ABCG2 transporter?
title_short Can bioluminescence resonance energy transfer be used to elucidate structural and binding information about the ABCG2 transporter?
title_sort can bioluminescence resonance energy transfer be used to elucidate structural and binding information about the abcg2 transporter?
topic ATP binding cassette G2
ABCG2
Bioluminescence resonance energy transfer
BRET
url https://eprints.nottingham.ac.uk/68414/