Nickel-catalysed synthesis of multisubstituted pyrroles by anti-carbometallative cyclisations

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Nickel-catalysed synthesis of multisubstituted pyrroles by anti-carbometallative cyclisations

Herein is presented the first example of nickel-catalysed cyclisation of Ntosylalkynamides with arylboronic acids to give 2,3,4-trisubstituted pyrroles. The reaction is initiated by alkyne arylnickelation and proceeds via an essential E/Z isomerisation step which allows for cyclisation. An investiga...

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Bibliographic Details
Main Author:	Gillbard, Simone Marie
Format:	Thesis (University of Nottingham only)
Language:	English
Published:	2019
Subjects:	pyrroles; lamellarins; nickel-catalysed synthesis
Online Access:	https://eprints.nottingham.ac.uk/56140/

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