Synthesis of pyrroles by nickel-catalysed arylative cyclisations of alkynamides

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Synthesis of pyrroles by nickel-catalysed arylative cyclisations of alkynamides

A nickel-based catalytic system for the anti-carbometallative cyclisations of alkynamides to arylboronic acids is described. The reactions proceed using catalytic nickel and (rac)-Ph-PHOX, to provide alkenylnickel species which can undergo reversible E/Z-isomerisation, followed by cyclisation onto a...

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Bibliographic Details
Main Author:	Chung, Chieh-Hsu
Format:	Thesis (University of Nottingham only)
Language:	English
Published:	2019
Subjects:	Nickel-based catalytic system; Pyrroles; Pyrrolyl propionic acid
Online Access:	https://eprints.nottingham.ac.uk/55874/

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