Highly-dispersed nickel nanoparticles decorated titanium dioxide nanotube array for enhanced solar light absorption

Honeycomb titanium dioxide nanotube array (TiO2-NTA) decorated by highly-dispersed nickel nanoparticles (Ni-NPs) has been grown under control on Ti foil by anodization and subsequent electrodeposition. The pore diameter and length of TiO2-NTA, and the size and quantity of Ni-NPs can be controlled vi...

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Main Authors: Chen, Jian, Zhou, Yingke, Li, Ruizhi, Wang, Xi, Chen, George Z.
Format: Article
Language:English
Published: Elsevier 2019
Subjects:
Online Access:https://eprints.nottingham.ac.uk/55308/
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author Chen, Jian
Zhou, Yingke
Li, Ruizhi
Wang, Xi
Chen, George Z.
author_facet Chen, Jian
Zhou, Yingke
Li, Ruizhi
Wang, Xi
Chen, George Z.
author_sort Chen, Jian
building Nottingham Research Data Repository
collection Online Access
description Honeycomb titanium dioxide nanotube array (TiO2-NTA) decorated by highly-dispersed nickel nanoparticles (Ni-NPs) has been grown under control on Ti foil by anodization and subsequent electrodeposition. The pore diameter and length of TiO2-NTA, and the size and quantity of Ni-NPs can be controlled via modulating the variables of the electrochemical processes. It has been found that the pretreatment of TiO2-NTA in the Cu(NO3)2 solution and further annealing at 450 °C in air could greatly improve the dispersion of the electrodeposited Ni-NPs. Absorption of the light in the solar spectrum from 300 to 2500 nm by the Ni-NPs@TiO2-NTA is as high as 96.83%, thanks to the co-effect of the light-trapping of TiO2-NTA and the plasmonic resonance of Ni-NPs. In the water heating experiment performed under an illuminating solar power density of ∼1 kW m−2 (AM 1.5), the ultimate temperature over 66 °C and an overall efficiency of 78.9% within 30 min were obtained, promising for applications in photothermal conversion and solar energy harvest.
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spelling nottingham-553082020-09-11T04:30:14Z https://eprints.nottingham.ac.uk/55308/ Highly-dispersed nickel nanoparticles decorated titanium dioxide nanotube array for enhanced solar light absorption Chen, Jian Zhou, Yingke Li, Ruizhi Wang, Xi Chen, George Z. Honeycomb titanium dioxide nanotube array (TiO2-NTA) decorated by highly-dispersed nickel nanoparticles (Ni-NPs) has been grown under control on Ti foil by anodization and subsequent electrodeposition. The pore diameter and length of TiO2-NTA, and the size and quantity of Ni-NPs can be controlled via modulating the variables of the electrochemical processes. It has been found that the pretreatment of TiO2-NTA in the Cu(NO3)2 solution and further annealing at 450 °C in air could greatly improve the dispersion of the electrodeposited Ni-NPs. Absorption of the light in the solar spectrum from 300 to 2500 nm by the Ni-NPs@TiO2-NTA is as high as 96.83%, thanks to the co-effect of the light-trapping of TiO2-NTA and the plasmonic resonance of Ni-NPs. In the water heating experiment performed under an illuminating solar power density of ∼1 kW m−2 (AM 1.5), the ultimate temperature over 66 °C and an overall efficiency of 78.9% within 30 min were obtained, promising for applications in photothermal conversion and solar energy harvest. Elsevier 2019-01-15 Article PeerReviewed application/pdf en cc_by_nc_nd https://eprints.nottingham.ac.uk/55308/1/Revised%20manuscript%20without%20marked%20changes.pdf Chen, Jian, Zhou, Yingke, Li, Ruizhi, Wang, Xi and Chen, George Z. (2019) Highly-dispersed nickel nanoparticles decorated titanium dioxide nanotube array for enhanced solar light absorption. Applied Surface Science, 464 . pp. 716-724. ISSN 0169-4332 Titanium dioxide nanotube array; Nickel nanoparticles; Plasmonic resonance; Light absorption; Photothermal conversion http://dx.doi.org/10.1016/j.apsusc.2018.09.091 doi:10.1016/j.apsusc.2018.09.091 doi:10.1016/j.apsusc.2018.09.091
spellingShingle Titanium dioxide nanotube array; Nickel nanoparticles; Plasmonic resonance; Light absorption; Photothermal conversion
Chen, Jian
Zhou, Yingke
Li, Ruizhi
Wang, Xi
Chen, George Z.
Highly-dispersed nickel nanoparticles decorated titanium dioxide nanotube array for enhanced solar light absorption
title Highly-dispersed nickel nanoparticles decorated titanium dioxide nanotube array for enhanced solar light absorption
title_full Highly-dispersed nickel nanoparticles decorated titanium dioxide nanotube array for enhanced solar light absorption
title_fullStr Highly-dispersed nickel nanoparticles decorated titanium dioxide nanotube array for enhanced solar light absorption
title_full_unstemmed Highly-dispersed nickel nanoparticles decorated titanium dioxide nanotube array for enhanced solar light absorption
title_short Highly-dispersed nickel nanoparticles decorated titanium dioxide nanotube array for enhanced solar light absorption
title_sort highly-dispersed nickel nanoparticles decorated titanium dioxide nanotube array for enhanced solar light absorption
topic Titanium dioxide nanotube array; Nickel nanoparticles; Plasmonic resonance; Light absorption; Photothermal conversion
url https://eprints.nottingham.ac.uk/55308/
https://eprints.nottingham.ac.uk/55308/
https://eprints.nottingham.ac.uk/55308/