Remote nucleophilic allylation by allylrhodium chain walking

Metal migration through a carbon chain is a versatile method for achieving remote functionalization. However, almost all known examples involve the overall net migration of alkylmetal species. Here, we report that allylrhodium species obtained from hydrorhodation of 1,3-dienes undergo chain walking...

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Bibliographic Details
Main Authors: Groves, Alistair, Martinez, Jose I., Smith, Joshua J., Lam, Hon Wai
Format: Article
Published: Wiley 2018
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Online Access:https://eprints.nottingham.ac.uk/53051/